Deuterofullerene C_(60)D_(24) studied by XRD, IR and XPS

B.P.Tarasov; Yu.M.Shulga; V.N.Fokin

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Deuterofullerene C_(60)D_(24) studied by XRD, IR and XPS

机译：XRD，IR和XPS研究的氘富勒烯C_（60）D_（24）

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The deuterofullerene C_(60)D_(24) was prepared from the solid C_(60) and was characterised by means of XRD, IR and XPS. The C_(60)D_(24) was found to be a polycrystalline powder with a FCC lattice and a =14.55 A. Deuterium thermal desorption from C_(60)D_(24) leads to a reversible formation of fullerene. However, the distances between the C_(60) molecules become significantly longer compared to the initial fullerite.

机译：由固体C_（60）制备氘代富勒烯C_（60）D_（24），并通过XRD，IR和XPS对其进行表征。发现C_（60）D_（24）是具有FCC晶格且a ＝ 14.55A的多晶粉末。氘从C_（60）D_（24）的热脱附导致富勒烯的可逆形成。但是，C_（60）分子之间的距离与初始富勒石相比变得明显更长。

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《Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics》 |2001年第2期|共5页
作者
B.P.Tarasov; Yu.M.Shulga; V.N.Fokin;
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正文语种 eng
中图分类合金学与各种性质合金;金属材料;
关键词
fullerenes; gas solid reaction; crystal structure; photoelectron spectroscopy; optical properties;

机译：富勒烯气固反应晶体结构光电子能谱光学性质;

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1. Deuterofullerene C_(60)D_(24) studied by XRD, IR and XPS [J] . B.P.Tarasov, Yu.M.Shulga, V.N.Fokin Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics . 2001,第1a2期

机译：XRD，IR和XPS研究的氘富勒烯C_（60）D_（24）
2. Theoretical and Experimental Study of Fullerenol Molecules and Ions C_(60)(OH)_(24-n)(OL)_n and C_(60)(OH)_(24-n)(OL)_nL~+ Successively Substituted by Alkali Metal Atoms L (n = 1-24) [J] . O. P. Charkin, N. M. Klimenko, Y.-S. Wang, Russian Journal of Inorganic Chemistry . 2011,第4期

机译：富勒烯醇分子和离子C_（60）（OH）_（24-n）（OL）_n和C_（60）（OH）_（24-n）（OL）_nL〜+连续被碱取代的理论和实验研究金属原子L（n = 1-24）
3. Features of the oxidation of C_(60) and C_(70) fullerites as studied by IR spectroscopy [J] . Ladyanov V.I., Aksenova V.V., Nikonova R.M. Russian Journal of Physical Chemistry . 2010,第9期

机译：红外光谱研究C_（60）和C_（70）富勒石的氧化特征
4. VIBRATIONAL SPECTRA AND MOLECULAR STRUCTURE OF THE HYDROFULLERENES C_(60)H_(18), C_(60)D_(18), AND C_(60)H_(36) AS STUDIED BY IR AND RAMAN SPECTROSCOPY AND FIRST-PRINCIPLE CALCULATIONS [C] . A.A. POPOV, V.V. SENYAVIN, A.A. GRANOVSKY, NATO Advanced Research Workshop on Hydrogen Materials Science and Chemistry of Carbon Nanomaterials; 20030914-20; Sudak, Crimea(UA) . 2003

机译：红外和拉曼光谱及第一性原理研究的富勒烯C_（60）H_（18），C_（60）D_（18）和C_（60）H_（36）的振动光谱和分子结构
5. Investigation of disorder, polymorphism, and packing in the crystal structures of C(60)-4C(6)H(6) and eta(2)-C(60)(Ir(CO)Cl(PR(3))(2))(2)-nC(6)H(6) [D] . Noll, Bruce Clifford 1999

机译：研究C（60）-4C（6）H（6）和eta（2）-C（60）（Ir（CO）Cl（PR（3））（2）的晶体结构中的无序，多态性和堆积））（2）-nC（6）H（6）
6. Composition-dependent structure of polycrystalline magnetron-sputtered V–Al–C–N hard coatings studied by XRD XPS XANES and EXAFS [O] . Bärbel Krause, Susan Darma, Marthe Kaufholz, -1

机译：XRDXPSXANES和EXAFS研究的多晶磁控溅射V–Al–C–N硬涂层的成分依赖性结构
7. Lattice distortion and energy level structures in doped C_{60} and C_{70} studied with the extended Su-Schrieffer-Heeger model: Polaron excitations and optical absorption [O] . Harigaya, Kikuo 1992

机译：掺杂C_ {60}和C_ {60}中的晶格畸变和能级结构 C_ {70}研究了扩展的su-schrieffer-Heeger模型：polaron 激发和光学吸收

Deuterofullerene C_(60)D_(24) studied by XRD, IR and XPS

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