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首页> 外文期刊>Journal of chemical crystallography >The preparation and crystal structures of some tricarbonylmanganese(I) octahedral complexes containing the 1,1-dimethylamino-2,2-diphenylphosphinoethane ligand
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The preparation and crystal structures of some tricarbonylmanganese(I) octahedral complexes containing the 1,1-dimethylamino-2,2-diphenylphosphinoethane ligand

机译:含1,1-二甲基氨基-2,2-二苯基膦基乙烷配体的三羰基锰(I)八面体配合物的制备和晶体结构

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摘要

Four new complexes of (pn) the titled ligand have been prepared and characterized: (CO)(3)Mn(pn)Br, 1; (CO)(3)Mn(pn)N-3, 2; the triazalato (tz) complex, (CO)(3)Mn(pn)(tz), 3 and [(CO)(4)Mn(pn)]BF4, 4. Crystal structures for the first three of these were determined. Crystal data for 1, monoclinic crystal system, space group=C2, a=17.9587(6) Angstrom, b=7.9611(3) Angstrom, c=14.2349(4) Angstrom, beta=90.281(1)degrees, V=2023.82(12) Angstrom(3), Z=4; for 2, monoclinic crystal system, space group=P2(1)/c, a=8.8933(14) Angstrom, b=13.844(2) Angstrom, c=16.361(3) Angstrom, beta=95.712(3)degrees, V=2004.4(6) Angstrom(3), Z=4; for 3, orthorhombic crystal system, space group=Pbca, a=17.9097(4)Angstrom, b=13.1308(4) Angstrom, c=21.2838(6) Angstrom, v=5005.3(2)Angstrom(3), Z=8.
机译:已经制备并表征了四个新的(pn)标题配体的配合物:(CO)(3)Mn(pn)Br,1;和(n)。 (CO)(3)Mn(pn)N-3,2;合成了三氮杂(tz)配合物(CO)(3)Mn(pn)(tz)3和[(CO)(4)Mn(pn)] BF4,4。确定了其中前三个的晶体结构。 1个单斜晶体系统的晶体数据,空间群= C2,a = 17.9587(6)埃,b = 7.9611(3)埃,c = 14.2349(4)埃,beta = 90.281(1)度,V = 2023.82( 12)埃(3),Z = 4;对于2,单斜晶系,空间群= P2(1)/ c,a = 8.8933(14)埃,b = 13.844(2)埃,c = 16.361(3)埃,beta = 95.712(3)度,V = 2004.4(6)埃(3),Z = 4;对于3,正交晶体系统,空间群= Pbca,a = 17.9097(4)埃,b = 13.1308(4)埃,c = 21.2838(6)埃,v = 5005.3(2)埃(3),Z = 8 。

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