Synthesis, Structure and Theoretical Research of a New Triaryl Phosphine Complex [HgCl2(PPh(2)Bz)(2)] (PPh(2)Bz = Benzyldiphenylphosphine)

Zhang N; Liu XC; Niu YY; Hou HW; Zhang HY; Wang QL; Zhao XP; Lue XR

首页> 外文期刊>Journal of chemical crystallography >Synthesis, Structure and Theoretical Research of a New Triaryl Phosphine Complex [HgCl2(PPh(2)Bz)(2)] (PPh(2)Bz = Benzyldiphenylphosphine)

【24h】

Synthesis, Structure and Theoretical Research of a New Triaryl Phosphine Complex [HgCl2(PPh(2)Bz)(2)] (PPh(2)Bz = Benzyldiphenylphosphine)

机译：新型三芳基膦配合物[HgCl2（PPh（2）Bz）（2）]（PPh（2）Bz =苄基二苯基膦）的合成，结构和理论研究

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The solution-phase reaction of HgCl2 with benzyldiphenylphosphine (PPh(2)Bz) yields a new triaryl phosphine complex [HgCl2(PPh(2)Bz)(2)] (1) with the bigger P-Hg-P angle, the longer Hg-Cl bond, and the shorter Hg-P bond. Comparison of the sensitive bond parameters with similar compounds and the theoretical calculation show that the sigma-donating abilities of tertiaryl phosphine ligands toward HgCl2 conforms to the following order: PEt3 > PPh(2)Bz > P(2-thienyl)(3) > dppf > PPh3.

机译：HgCl2与苄基二苯基膦（PPh（2）Bz）的溶液相反应生成新的三芳基膦配合物[HgCl2（PPh（2）Bz）（2）]（1），P-Hg-P角越大，时间越长Hg-Cl键和较短的Hg-P键。与相似化合物的敏感键参数比较和理论计算表明，叔芳基膦配体对HgCl2的sigma供电能力符合以下顺序：PEt3> PPh（2）Bz> P（2-噻吩基）（3）> dppf> PPh3。

著录项

来源
《Journal of chemical crystallography》 |2009年第1期|共5页
作者
Zhang N; Liu XC; Niu YY; Hou HW; Zhang HY; Wang QL; Zhao XP; Lue XR;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类晶体学;
关键词
Tertiary phosphine ligand; Mercury(II) complex; Theoretical research;

机译：叔膦配体;汞（II）配合物;理论研究;

相似文献

外文文献
中文文献
专利

1. Synthesis, Structure and Theoretical Research of a New Triaryl Phosphine Complex [HgCl2(PPh(2)Bz)(2)] (PPh(2)Bz = Benzyldiphenylphosphine) [J] . Zhang N, Liu XC, Niu YY, Journal of chemical crystallography . 2009,第1期

机译：新型三芳基膦配合物[HgCl2（PPh（2）Bz）（2）]（PPh（2）Bz =苄基二苯基膦）的合成，结构和理论研究
2. Comparison of the neutral benzyldiphenylphosphine complexes C6H6Cr(CO)(2)PPh(2)Bz and C5H5Mn(CO)(2)PPh(2)Bz with the isoelectronic manganiobenzyldiphenylphosphonium salts[C5R5Mn(CO)(NO)PPh(2)Bz]BF4 [J] . Geicke J., Polbom K., Lorenz IP. Inorganica Chimica Acta . 1998,第1a2期

机译：中性苄基二苯基膦配合物C6H6Cr（CO）（2）PPh（2）Bz和C5H5Mn（CO）（2）PPh（2）Bz与等电子锰苄基二苯基phosph盐[C5R5Mn（CO）（NO）PPh（2）Bz]的比较高炉4
3. Rhodium and iridium complexes with thiolate and tertiary phosphine ligands. The synthesis and structures of trans-[Ir(SC6H3Cl2-2,6)(CO)(PPh3)(2)], [Rh-2(mu-SC6H3Pr3i-2,4,6)(2)(CO)(2)-(PPh3)(2)], [Rh2H2(mu-SC6H4PPh2-2)(2)(CO)(2)(PPh3)(2)][BF4](2), and [J] . Dilworth JR., Zheng YF., Morales D. Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry . 2000,第17期

机译：铑和铱与硫醇盐和叔膦配体的配合物。反式[Ir（SC6H3Cl2-2,6）（CO）（PPh3）（2）]，[Rh-2（mu-SC6H3Pr3i-2,4,6）（2）（CO）（2）的合成和结构）-（PPh3）（2）]，[Rh2H2（mu-SC6H4PPh2-2）（2）（CO）（2）（PPh3）（2）] [BF4]（2）和
4. Synthesis and Crystal Structure of μ3-H(Ph)C=CFeCo2(CO)7dppe(deep=Ph2PCH2CH2PPh2) and (μ3-S)FeCo2(CO)7dppfe(dppfe= Ph2PC5H4PPh2) [C] . Yibin Wang 11th International Symposium of Fine Chemistry and Functional Polymers Jul 28-31, 2001 Hailar, Inner Mongolia, P.R. China . 2001

机译：μ3-H（Ph）C = C FeCo2（CO）7dppe（深= Ph2PCH2CH2PPh2）和（μ3-S）FeCo2（CO）7dppfe（dppfe = Ph2PC5H4PPh2）的合成和晶体结构
5. Synthesis and study of transition metal silylene complexes and development of iridium chemistry featuring the tripodal anionic phosphine (PhB(CH(2)PPh(2))3-) ligand. [D] . Feldman, Jay Dell. 2002

机译：合成和过渡金属亚甲硅烷基络合物的研究和铱化学的发展与三脚架阴离子膦（PhB（CH（2）PPh（2））3-）配体。
6. Syntheses Reactivities Characterization and Crystal Structures of Dipalladium Complexes Containing the 13-pyrimidinyl Ligand: Structures of Pd(PPh3)(Br)2(μη2-C4H3N2)2 Pd(Br)2(μη2-Hdppa)2 and {Pd(PPh3)(CH3CN)}2(μη2-C4H3N2)2BF42 [O] . Hsiao-Fen Wang, Kuang-Hway Yih, Gene-Hsiang Lee 2020

机译：含有13-嘧啶基配体的偶氮配合物的合成重荷表征和晶体结构：Pd（PPH3）（Br） 2（μη2-C4H3N2）2Pd（Br） 2（ μη2-hdppa）2和{pd（pph3）（ch 3cn）} 2（μη2-c4h3n2）2 bf4 2
7. Synthesis of a New Multidentate Phosphane Ligand C6H2(CH2PPh2)4-1,2,4,5 − X-ray Structure of a Dinuclear Ruthenium(II)-Bridged Complex: {RuCl2(PPh3)}2{C6H2(CH2PPh2)4-1,2,4,5-P,P′,P′′,P′′′} [O] . Pablo Steenwinkel, Sebastiaan Kolmschot, Robert A. Gossage, 1998

机译：单核钌（II） - 近核钌（II）的新多型磷酸膦配体C6H2（CH2PPH2）4-1,2,5 - X射线结构的合成：{RuCl2（PPH3）} 2 {C6H2（CH2PPH2）4 -1,2,4,5-p，p'，p'，p''}
8. Synthesis and X-ray Crystal Structures of (Au(CH2)2PPh2)2(CF3)2, (Au(CH2)2PPh2)2(C6F5)2, and (PPN)(Au(C6F5)4): Two Dinuclear Gold (II) Ylide Complexes Containing Alkyl and Aryl Ligands and a Tetrakis(pentafluorophenyl)aurate(III) [R] . Murray, H. H., Fackler, J. P., Porter, L. C., 1987

机译：（au（CH2）2pph2）2（CF3）2，（au（CH2）2pph2）2（C6F5）2和（ppN）（au（C6F5）4）的合成和X射线晶体结构：两个双核金（ II）含有烷基和芳基配体的Ylide配合物和四（五氟苯基）丙酸酯（III）

Synthesis, Structure and Theoretical Research of a New Triaryl Phosphine Complex [HgCl2(PPh(2)Bz)(2)] (PPh(2)Bz = Benzyldiphenylphosphine)

摘要

著录项

相似文献

相关主题

期刊订阅