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Structural changes induced by heavy ion irradiation in titanium silicon carbide

机译:钛碳化硅中重离子辐照引起的结构变化

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Carbide-type ceramics, which have remarkable thermomechanical properties, are sensed to manufacture the fuel cladding of Generation IV reactors that should work at high temperature. The MAX phases, and more particularly titanium silicon carbide, are distinguished from other materials by their ability to have some plasticity, even at room temperature. For this study, polycrystalline Ti3SiC2 was irradiated with ions of different energies, which allow to discriminate the effect of both electronic and nuclear interactions. After characterization by low-incidence X-ray diffraction and cross-sectional transmission electron microscopy, it appears that Ti3SiC2 is not sensitive to electronic excitations while nuclear shocks damage its structure. The results show the creation of many defects and disorder in the structure, an expansion of the hexagonal close-packed lattice along the c axis, and an increase in the microstrain yield.
机译:具有出色的热机械性能的碳化物型陶瓷被认为可以制造第四代反应堆的燃料包壳,该燃料包壳应在高温下工作。 MAX相,尤其是碳化钛硅,与其他材料的不同之处在于,即使在室温下,它们也具有一定的可塑性。对于本研究,用不同能量的离子辐照多晶Ti3SiC2,可以区分电子相互作用和核相互作用的影响。通过低入射X射线衍射和横截面透射电子显微镜进行表征后,看来Ti3SiC2对电子激发不敏感,而核冲击会破坏其结构。结果表明,在结构中产生了许多缺陷和混乱,六角形密堆积晶格沿c轴扩展,微应变产率提高。

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