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Stress-corrosion mechanisms in silicate glasses

机译:硅酸盐玻璃中的应力腐蚀机理

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The present review is intended to revisit the advances and debates in the comprehension of the mechanisms of subcritical crack propagation in silicate glasses almost a century after its initial developments. Glass has inspired the initial insights of Griffith into the origin of brittleness and the ensuing development of modern fracture mechanics. Yet, through the decades the real nature of the fundamental mechanisms of crack propagation in glass has escaped a clear comprehension which could gather general agreement on subtle problems such as the role of plasticity, the role of the glass composition, the environmental condition at the crack tip and its relation to the complex mechanisms of corrosion and leaching. The different processes are analysed here with a special focus on their relevant space and time scales in order to question their domain of action and their contribution in both the kinetic laws and the energetic aspects.
机译:本综述旨在回顾硅酸盐玻璃在其初步发展后近一个世纪对亚临界裂纹扩展机理的理解和进展。 Glass启发了格里菲斯(Griffith)对脆性的起源以及随之而来的现代断裂力学发展的初步见解。然而,在过去的几十年中,玻璃中裂纹扩展的基本机制的真实本质已经逃脱了清晰的理解,这可以使人们对诸如塑性作用,玻璃成分的作用,裂纹的环境条件等细微问题达成共识。尖端及其与腐蚀和浸出的复杂机理的关系。这里对不同的过程进行了分析,并特别关注它们的相关空间和时间尺度,以质疑它们的作用域以及它们在动力学定律和能量方面的贡献。

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