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首页> 外文期刊>Journal of Physics, D. Applied Physics: A Europhysics Journal >White-emitting organic diode with a doped blocking layer between hole- and electron-transporting layers
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White-emitting organic diode with a doped blocking layer between hole- and electron-transporting layers

机译:白色发光有机二极管,在空穴传输层和电子传输层之间具有掺杂的阻挡层

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摘要

A new white-emitting organic diode was realized simply by inserting a doped hole-blocking layer between the hole-transporting layer (HTL) and the electron-transporting layer (ETL). The structure of this device is ITO/CuPc/NPB/blocking layer:rubrene/Alq/MgAg. Copper phthalocyanine (CuPc) was used as a buffer layer; N,N'-bis-(1-naphthyl)-N,N'-diphenyl-1.1'-biphenyl-4-4'-diamine (NPB) was the HTL; the tris(8-quinolinolato)aluminium complex (Alq) was the ETL; and the trimer of N-arylbenzimidazole (TPBi), 2-(4-biphenylyl-5-(4-tertbutylphenyl)-1,2,3-oxadiazole (PBD) or the 1,2,4-triazole derivative (TAZ) were used as the blocking layers, in which rubrene is doped. The emission spectrum of this device covers a wide range of the visible region and can be sensitively adjusted by the concentration of rubrene. The white emission with CIE (Commission international de l'Eclairage) coordinates x = 0.31, y = 0.32, a maximum luminance of 8635 cd m(-2) and maximum luminous efficiency 1.39 lm w(-1) (4.9 V) were obtained in the device with a concentration of 1.5% rubrene in TPBi. [References: 10]
机译:只需在空穴传输层(HTL)和电子传输层(ETL)之间插入掺杂的空穴阻挡层,即可实现一种新的发白光有机二极管。该器件的结构为ITO / CuPc / NPB /阻挡层:鲁宾/ Alq / MgAg。酞菁铜(CuPc)用作缓冲层; N,N′-双-(1-萘基)-N,N′-二苯基-1.1′-联苯-4-4′-二胺(NPB)为HTL。三(8-喹啉基脲)铝配合物(Alq)为ETL; N-芳基苯并咪唑(TPBi),2-(4-联苯基-5-(4-叔丁基苯基)-1,2,3-恶二唑(PBD)或1,2,4-三唑衍生物(TAZ)的三聚体分别为用作掺杂红荧烯的阻挡层。该器件的发射光谱覆盖可见光范围广,可以通过红荧烯的浓度进行灵敏地调节。CIE(国际照明委员会)的白光发射坐标x = 0.31,y = 0.32,在TPBi中浓度为1.5%的re中,获得的最大亮度为8635 cd m(-2),最大发光效率为1.39 lm w(-1)(4.9 V)。 [参考:10]

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