Synthesis of new carbazole substituted fullerene derivative as an electron acceptor for bulk heterojunction organic photovoltaic cell applications

Sakthivel Pachagounder; Kumar S. K. Ashok; Thangamuthu R.; Jin Sung-Ho

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Synthesis of new carbazole substituted fullerene derivative as an electron acceptor for bulk heterojunction organic photovoltaic cell applications

机译：新型咔唑取代的富勒烯衍生物作为本体异质结有机光伏电池应用的电子受体的合成

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We design and synthesized 9-hexyl carbazole-3-C-61-butric acid methyl ester, (HCvz-C61BM) carbazole based fullerene acceptor derivative used for photovoltaic cell applications. The synthesized HCvz-C61BM acceptor freely soluble in common organic solvents such as CHCl3, CH2Cl2, THF, ODCB and it showed higher LUMO of -3.63 eV. The HCvz-C61BM acceptor showed higher thermal stability of 413 degrees C. The organic photovoltaic device was fabricated with the configuration of ITO/PEDOT/P3HT : HCvz-C61BM/LiF/Al. It shows the best performance for 1 : 2 weight ratio of P3HT : HCvz-C61BM with PCE of 1.74%, Jsc of 6.19 mA/cm(2), Voc of 0.78 V and FF of 37%.

机译：我们设计并合成了用于光伏电池的基于9-己基咔唑-3-C-61-丁二酸甲酯（HCvz-C61BM）咔唑的富勒烯受体衍生物。合成的HCvz-C61BM受体可自由溶于常见的有机溶剂，如CHCl3，CH2Cl2，THF，ODCB，并且其LUMO值较高，为-3.63 eV。 HCvz-C61BM受体在413摄氏度下显示出更高的热稳定性。有机光伏器件的制造工艺为ITO / PEDOT / P3HT：HCvz-C61BM / LiF / Al。对于P3HT：HCvz-C61BM的1：2重量比，PCE为1.74％，Jsc为6.19 mA / cm（2），Voc为0.78 V，FF为37％，它显示出最佳性能。

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《Journal of the Indian Chemical Society》 |2015年第6期|共3页
作者
Sakthivel Pachagounder; Kumar S. K. Ashok; Thangamuthu R.; Jin Sung-Ho;
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正文语种 eng
中图分类化学;
关键词
Organic photovoltaics; carbazole; fullerene; PCBM;

机译：有机光伏;咔唑;富勒烯;PCBM;

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1. Synthesis of new carbazole substituted fullerene derivative as an electron acceptor for bulk heterojunction organic photovoltaic cell applications [J] . Sakthivel Pachagounder, Kumar S. K. Ashok, Thangamuthu R., Journal of the Indian Chemical Society . 2015,第6期

机译：新型咔唑取代的富勒烯衍生物作为本体异质结有机光伏电池应用的电子受体的合成
2. Thermally stable organic bulk heterojunction photovoltaic cells incorporating an amorphous fullerene derivative as an electron acceptor [J] . Kim S.-O., Sung Chung D., Cha H., Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion . 2011,第2期

机译：包含非晶富勒烯衍生物作为电子受体的热稳定有机体异质结光伏电池
3. Bis(tri-n-alkylsilyl oxide) silicon phthalocyanines: a start to establishing a structure property relationship as both ternary additives and non-fullerene electron acceptors in bulk heterojunction organic photovoltaic devices [J] . Dang Minh-Trung, Grant Trevor M., Yan Han, Journal of Materials Chemistry, A. Materials for energy and sustainability . 2017,第24期

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4. Bulk heterojunction organic photovoltaic devices containing silicon phthalocyanine as a non-fullerene electron acceptor [C] . Kayden L. C. Kaller, Trevor J. Coathup, Trevor M. Grant, IEEE Photovoltaic Specialists Conference . 2020

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Synthesis of new carbazole substituted fullerene derivative as an electron acceptor for bulk heterojunction organic photovoltaic cell applications

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