首页> 外文期刊>Journal of the Indian Chemical Society >Microwave-assisted synthesis, spectroscopy and antimicrobial studies of mono(cyclopentadienyl)titanium(IV) derivatives of bis(Schiff bases) derived from 14'-diacetyIferrocene and 3-substituted phenyl-4-amino-5-mercapto-1,2,4-triazoles
【24h】

Microwave-assisted synthesis, spectroscopy and antimicrobial studies of mono(cyclopentadienyl)titanium(IV) derivatives of bis(Schiff bases) derived from 14'-diacetyIferrocene and 3-substituted phenyl-4-amino-5-mercapto-1,2,4-triazoles

机译:微波辅助合成,光谱学和抗微生物研究的双(席夫碱)的双(环戊二烯基)钛(IV)衍生物从14'-二乙二茂铁和3-取代的苯基-4-氨基-5-巯基-1,2,4 -三唑

获取原文
获取原文并翻译 | 示例
           

摘要

The reactions of mono(cyclopentadienyl)titanium(IV) trichloride with a new class of Schiff bases (H2L), derived by condensing 1,1'-diacetyIferrocene with different 3-substituted phenyl-4-amino-5-mercapto-1,2,4-triazoles, have been studied both by a conventional stirring method and also using microwave technology. Binuclear products of type [{η~5s-C5Hs)TiCl2}2 (L)] have been isolated in both cases. Tentative structural conclusions are drawn for the reaction products based upon analysis, electrical conductance, magnetic moment and spectral (UV-Visible, IR, ~1H NMR and ~(13)C NMR) data. FAB mass spectra of complexes were also recorded to confirm the binuclear structures. Studies were conducted to assess the growth inhibiting potential of the ligands and complexes against various fungal and bacterial strains.
机译:三氯化单(环戊二烯基)钛(IV)与新型席夫碱(H2L)的反应是通过将1,1'-二乙If二茂铁与不同的3-取代的苯基-4-氨基-5-巯基-1,2缩合而得已经通过常规搅拌方法和还使用微波技术研究了α,4-三唑。在两种情况下均已分离出类型为[{η〜5s-C5Hs)TiCl2} 2(L)的双核产物。根据分析,电导率,磁矩和光谱(UV-Visible,IR,〜1H NMR和〜(13)C NMR)数据得出了反应产物的初步结构结论。还记录了复合物的FAB质谱,以确认双核结构。进行了研究以评估配体和复合物对各种真菌和细菌菌株的生长抑制潜力。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号