Transition metal complexes with pyrazole based ligands - Part XXV. Deaquation of isostructural cobalt(II) and nickel(II) complexes with 3,5-dimethylpyrazole-1-carboxamidine

Szecsenyi KM; Leovac VM; Petkovic R; Jacimovic ZK; Pokol G

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Transition metal complexes with pyrazole based ligands - Part XXV. Deaquation of isostructural cobalt(II) and nickel(II) complexes with 3,5-dimethylpyrazole-1-carboxamidine

机译：具有吡唑基配体的过渡金属配合物-第XXV部分。用3,5-二甲基吡唑-1-羧am将同构钴（II）和镍（II）络合物脱氨

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The deaquation of two isostructural compounds of general formula [M(HL)(2)(H2O)(2)](NO3)(2) (M=Co, Ni, HL=3,5-dimethyl-1H-pyrazole-1-carboxamidine) is discussed in the view of their crystal and molecular structure. The compounds contain the same number and type of hydrogen bonds of the adjacent nitrate ions, only in the opposite orientation. On the basis of their deaquation pattern such a small difference may be detected, i.e., methods of thermal analysis are sensitive enough to show very small structural differences.

机译：通式[M（HL）（2）（H2O）（2）]（NO3）（2）的两种同构化合物的脱去（M = Co，Ni，HL = 3,5-二甲基-1H-吡唑-1 （羧甲idine）从它们的晶体和分子结构的角度进行讨论。这些化合物仅在相反的方向上包含相邻硝酸根离子相同数量和类型的氢键。根据它们的脱水模式，可以检测到这样的小差异，即，热分析方法足够灵敏以显示非常小的结构差异。

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《Journal of thermal analysis and calorimetry》 |2007年第3期|共4页
作者
Szecsenyi KM; Leovac VM; Petkovic R; Jacimovic ZK; Pokol G;
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正文语种 eng
中图分类分析化学;
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Co(II) and Ni(II) complexes; crystal structure; deaquation; 3; 5-dimethyl-1H-pyrazole-1-carboxamidine; THERMAL-PROPERTIES; CO(II); NI(II); HALIDES; CU(II); CD(II); ZN(II); ACID; XRD;

机译：Co（II）和Ni（II）配合物;晶体结构;脱氢;3;5-二甲基-1H-吡唑-1-羧am;热性质;CO（II）;NI（II）;卤化物;CU（II）;CD（II）;ZN（II）;ACID;XRD;

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1. Transition metal complexes with pyrazole based ligands - Part XXV. Deaquation of isostructural cobalt(II) and nickel(II) complexes with 3,5-dimethylpyrazole-1-carboxamidine [J] . Szecsenyi KM, Leovac VM, Petkovic R, Journal of thermal analysis and calorimetry . 2007,第3期

机译：具有吡唑基配体的过渡金属配合物-第XXV部分。用3,5-二甲基吡唑-1-羧am将同构钴（II）和镍（II）络合物脱氨
2. Transition Metal Complexes with Pyrazole Based Ligands part 15. Cobalt(III)-, nickel(II)- and copper(II)-complexes with 3,5-dimethyl-1-thiocarboxamidepyrazole [J] . K. Meszaros Szecsenyi, V. M. Leovac, Z. K. Jacimovic, Journal of thermal analysis and calorimetry . 2003,第3期

机译：带有吡唑基配体的过渡金属配合物，第15部分。钴（III）-，镍（II）-和铜（II）-配合物与3,5-二甲基-1-硫代羧酰胺吡唑的配合
3. Synthesis and characterization of a series of transition metal complexes with a new symmetrical polyoxaaza macroacyclic Schiff base ligand: X-ray crystal structure of cobalt(II) and nickel(II) complexes and their antibacterial properties [J] . Keypour H., Shayesteh M., Rezaeivala M., Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy . 2013,第Null期

机译：具有新型对称多恶唑大环席夫碱配体的一系列过渡金属配合物的合成与表征：钴（II）和镍（II）配合物的X射线晶体结构及其抗菌性能
4. Metallo-supramolecular Diblock Copolymers based on Heteroleptic Cobalt(III) and Nickel(II) Bis-terpyridine Complexes [C] . Clement Mugemana, Pierre Guillet, Stephanie Hoeppener, American Chemical Society . 2010

机译：基于异钴（III）和镍（II）双萜烯吡啶配合物的金属 - 超分子二嵌段共聚物
5. THE COMPLEXES OF IRON(II), COBALT(II), AND NICKEL(II) WITH LIGANDS CONTAINING THE CONJUGATED METHINE GROUP. [D] . STOUFER, ROBERT CARL. 1959

机译：铁（II），钴（II）和镍（II）的复合物含有共轭甲基基团。
6. Synthesis and Spectral Investigations of Manganese(II) Cobalt(II) Nickel(II) Copper(II) and Zinc(II) Complexes of New Polydentate Ligands Containing a 18-Naphthyridine Moiety [O] . Sreedasyam Jagannatha Swamy, Erra Ram Reddy, Devunuri Naga Raju, 2006

机译：新型含18-萘啶基多齿配体的锰（II）钴（II）镍（II）铜（II）和锌（II）配合物的合成和光谱研究
7. Transition-metal Complexes of Pyrrole Pigments. XII. Optical and Magnetic Resonance Spectra of the Cobalt(II) and Nickel(II) Complexes of 1,19-Disubstituted Tetradehydrocorrins [O] . Yukito Murakami, Kazunori Sakata, Yasuhiro Tanaka, 1975

机译：吡咯颜料的过渡金属配合物。 XII。钴（II）的光学和磁共振光谱和1,19二取代的四氢罗素的镍（II）复合物

Transition metal complexes with pyrazole based ligands - Part XXV. Deaquation of isostructural cobalt(II) and nickel(II) complexes with 3,5-dimethylpyrazole-1-carboxamidine

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