Extremely Base-Resistant Organic Phosphazenium Cations

Reinhard Schwesinger; Manfred Keller; Reinhard Link; Peter Wenzl; Sebastian Kossek

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Extremely Base-Resistant Organic Phosphazenium Cations

机译：极耐碱的有机磷鎓阳离子

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摘要

A series of peralkylated polyaminophosphazenium cations exhibiting extraordinary base resistance under phase-transfer conditions were efficiently synthesized from readily available starting materials.Their half lives under these conditions exceed those of the most stable conventional organic cations by factors of up to 3000.

机译：由易得的原料有效合成了一系列在相转移条件下表现出优异耐碱性的过烷基化聚氨基磷腈鎓阳离子，它们在这些条件下的半衰期比最稳定的常规有机阳离子高了3000倍。

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《Chemistry: A European journal》 |2006年第2期|共9页
作者
Reinhard Schwesinger; Manfred Keller; Reinhard Link; Peter Wenzl; Sebastian Kossek;
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正文语种 eng
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cations; phase-transfer catalysis; phosphazenes; phosphorus;

机译：阳离子;相转移催化;磷腈;磷;

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1. Extremely Base-Resistant Organic Phosphazenium Cations [J] . Reinhard Schwesinger, Manfred Keller, Reinhard Link, Chemistry: A European journal . 2006,第2期

机译：极耐碱的有机磷鎓阳离子
2. A Base-Resistant Zn-II-Based Metal-Organic Framework: Synthesis, Structure, Postsynthetic Modification, and Gas Adsorption [J] . He Tao, Zhang Yong-Zheng, Wang Bin, ChemPlusChem . 2016,第8期

机译：基于抗底座的Zn-II金属 - 有机框架：合成，结构，后盈改装和气体吸附
3. A Base-Resistant Zn-II-Based Metal-Organic Framework: Synthesis, Structure, Postsynthetic Modification, and Gas Adsorption [J] . He Tao, Zhang Yong-Zheng, Wang Bin, ChemPlusChem . 2016,第8期

机译：基于抗底座的Zn-II金属 - 有机框架：合成，结构，后盈改装和气体吸附
4. HIGHLY ACTIVE PHOSPHAZENIUM CHLORIDE CATALYST IMMOBILIZED ON SBA-15 MESOPOROUS MATERIAL IN THE CHLORINATION OF ALCOHOLS WITH PHOSGENE [C] . Keun-Sik Kim, O Zoon Kwon, Gon Seo International Zeolite Conference pt.C; 20040425-30; Cape Town(ZA) . 2004

机译：SBA-15介孔材料上固定化的高活性氯化磷催化剂，用光气氯化醇
5. Experimental and Theoretical Studies of Organic High-Spin Ions and Extremely Non-Rigid Ions [D] . Matsushita, Michio 1992

机译：有机高自旋离子和极非刚性离子的实验和理论研究
6. Base-Resistant Ionic Metal-Organic Framework as a Porous Ion-Exchange Sorbent [O] . Aamod V. Desai, Arkendu Roy, Partha Samanta, 2018

机译：耐碱离子金属有机骨架作为多孔离子交换吸附剂
7. Mesoporous Silica Materials with an Extremely High Content of Organic Sulfonic Groups and Their Comparable Activities with that of Concentrated Sulfuric Acid in Catalytic Esterification [O] . -1

机译：具有极高含量的有机磺酸含量的介孔二氧化硅材料及其在催化酯化中具有浓硫酸的可比活性

Extremely Base-Resistant Organic Phosphazenium Cations

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