The catalyzed desulfinylative allylation of carbonyl compounds with alk-2-enesulfonyl chlorides and silyl alk-2-enesulfinates

Volla C.M.R.; Markovi? D.; Laclef S.; Vogel P.

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The catalyzed desulfinylative allylation of carbonyl compounds with alk-2-enesulfonyl chlorides and silyl alk-2-enesulfinates

机译：羰基化合物与烷-2-烯磺酰氯和甲硅烷基烷-2-烯亚磺酸酯的催化脱硫烯丙基化

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Coupling up with sulfonyl chlorides: An ene reaction of alkenes with SO_2·BCl_3 permits the one-pot conversion of simple alkenes into b,g-unsaturated sulfonyl chlorides or sulfinic silyl esters. These compounds can then be used as nucleophilic allylating agents with aldehydes and ketones to generate the corresponding homoallylic alcohols (see scheme) with good chemo-and diastereoselectivity in the presence of a suitable catalyst and reducing agent.

机译：与磺酰氯的偶联：烯烃与SO_2·BCl_3的烯键反应可将简单的烯烃单锅转化为b，g-不饱和磺酰氯或亚磺酸甲硅烷基酯。这些化合物然后可以与醛和酮一起用作亲核烯丙基化剂，在合适的催化剂和还原剂存在下，生成具有良好的化学和非对映选择性的相应的均烯丙基醇（参见方案）。

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《Chemistry: A European journal》 |2010年第30期|共5页
作者
Volla C.M.R.; Markovi? D.; Laclef S.; Vogel P.;
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正文语种 eng
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关键词
Allylation; Ene reaction; Palladium; Sulfonyl chlorides; Umpolung;

机译：烯丙基化;烯反应;钯;磺酰氯;Umpolung;

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1. The Catalyzed Desulfinylative Allylation of Carbonyl Compounds with Alk-2-enesulfonyl Chlorides and Silyl Alk-2-enesulfinates [J] . Chandra M. R. Volla Dr. Dean Marković Dr. Sylvain Laclef Pierre Vogel Prof. Chemistry - A European Journal . 2010,第30期

机译：烷基-2-烯磺酰氯和烷基烷基-2-烯亚磺酸酯催化羰基化合物的脱硫烯丙基化
2. Ligandless Iron-Catalyzed Desulfinylative C–C Allylation Reactions using Grignard Reagents and Alk-2-enesulfonyl Chlorides [J] . Chandra M. R. Volla, Dean Markovic, Srinivas Reddy Dubbaka, European journal of organic chemistry . 2009,第36期

机译：使用格氏试剂和烷基-2-烯磺酰氯的无配体铁催化的脱硫羰基化CC烯丙基化反应
3. The Copper(I) Chloride-Catalyzed Reaction of Ketene Silyl Acetals or Silyl Enol Ethers with α-Halogen Substituted Allylsilanes to Form Carbonyl Compounds Bearing Vinylsilane Functionality [J] . Michiharu Mitani Masayuki Masuda Letters in Organic Chemistry . 2007,第3期

机译：铜（I）催化的乙炔甲硅烷基缩醛或甲硅烷基烯醇醚与α-卤素取代的烯丙基硅烷的反应形成具有乙烯基硅烷官能团的羰基化合物
4. Iridium-Catalyzed Carbonyl Allylation by Allylic Ethers with Tin(II) Chloride [C] . Masanori Marukawa, Yoshiro Masuyama Symposium on Organometallic Chemistry . 2006

机译：铱催化的羰基烯丙基通过烯丙基醚用锡（II）氯化物
5. Palladium-catalyzed decarboxylative allylations of ester enolate equivalents and palladium-catalyzed cyclizations via CO2 and silyl activation. [D] . Ariyarathna, Yamuna. 2014

机译：钯催化的酯烯酸酯等效物的脱羧烯丙基化和钯催化的经由CO2和甲硅烷基活化的环化反应。
6. Copper(II)-Catalyzed Silylation of Activated Alkynes in Water: Diastereodivergent Access to (E)- or (Z)-β-Silyl-αβ-Unsaturated Carbonyl and Carboxyl Compounds [O] . Joseph A. Calderone, Webster L. Santos -1

机译：铜（II）催化的水中活化炔烃的甲硅烷基化：（E）-或（Z）-β-甲硅烷基-αβ-不饱和羰基和羧基化合物的非对映异构通路
7. Palladium-catalyzed desulfinylative C–C allylation of Grignard reagents and enolates using allylsulfonyl chlorides and esters [O] . Chandra M. Rao Volla, Srinivas Reddy Dubbaka, Pierre Vogel 2009

机译：钯 - 催化的脱硫脱硫酸脱硫基烯丙基烯丙基和使用烯丙基氯酰氯和酯烯醇化合物

The catalyzed desulfinylative allylation of carbonyl compounds with alk-2-enesulfonyl chlorides and silyl alk-2-enesulfinates

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