Palladium-catalyzed borylation of aryl mesylates and tosylates and their applications in one-pot sequential suzuki-miyaura biaryl synthesis

Chow W.K.; So C.M.; Lau C.P.; Kwong F.Y.

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Palladium-catalyzed borylation of aryl mesylates and tosylates and their applications in one-pot sequential suzuki-miyaura biaryl synthesis

机译：钯催化芳基甲磺酸酯和甲苯磺酸酯的硼化及其在一锅顺序铃木-宫浦联芳基合成中的应用

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Top of the one-pots! The first palladium-catalyzed borylation of aryl tosylates and mesylates is described. The reaction conditions are mild and provide excellent functional-group compatibility (e.g., R=CN, CHO, COOMe, C(O)R, NH2, or NH-indole; see scheme). Pd/MeO-CM-phos allows one-pot sequential reactions in the preparation of unsymmetrical biaryls.

机译：一锅之巅！描述了芳基甲苯磺酸酯和甲磺酸酯的第一钯催化的硼化。反应条件温和并且提供优异的官能团相容性（例如，R ＝ CN，CHO，COOMe，C（O）R，NH 2或NH-吲哚;参见方案）。 Pd / MeO-CM-phos可以在不对称联芳基制备中进行一锅法顺序反应。

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《Chemistry: A European journal》 |2011年第25期|共5页
作者
Chow W.K.; So C.M.; Lau C.P.; Kwong F.Y.;
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正文语种 eng
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关键词
biaryls; borylation; cross-coupling; palladium; phosphine; tosylates;

机译：联芳基;硼化;交叉偶联;钯;膦;甲苯磺酸盐;

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1. Palladium-catalyzed borylation of aryl mesylates and tosylates and their applications in one-pot sequential suzuki-miyaura biaryl synthesis [J] . Chow W.K., So C.M., Lau C.P., Chemistry: A European journal . 2011,第25期

机译：钯催化芳基甲磺酸酯和甲苯磺酸酯的硼化及其在一锅顺序铃木-宫浦联芳基合成中的应用
2. Palladium nanoparticle catalysis: borylation of aryl and benzyl halides and one-pot biaryl synthesis via sequential borylation-Suzuki-Miyaura coupling [J] . Ansuman Bej, Dipankar Srimani, Amitabha Sarkar Green chemistry . 2012,第3期

机译：钯纳米颗粒催化：芳基和苄基卤化物的硼化和通过顺序硼化-Suzuki-Miyaura偶联进行一锅联芳基合成
3. Palladium-catalyzed borylation of m-dibromobenzene derivative and its applications in one-pot tandem Suzuki-Miyaura arenes synthesis [J] . Xie Dahai, Li Rong, Zhang Dengqing, Tetrahedron . 2015,第47期

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4. Suzuki-Miyaura Reaction Using Biphenylene-containing Ruthenocenylphosphine (R-Phos): Synthesis of Tetra-ortho-substituted Biaryl from Aryl Chloride [C] . Takashi Hoshi, Ippei Saitoh, Toshio Suzuki Symposium on Organometallic Chemistry . 2007

机译：铃木宫果酰胺反应使用含有联苯的钌烯基（R-PHOS）的反应：从芳氯的芳基的四右替代的芳丙齐芳基
5. Functionalized organotrifluoroborates: Synthesis and reactivity. I.Suzuki-Miyaura reactions of aryl- and heteroaryl trifluoroborates with aryl- and heteroaryl triflates. II. Oxidation of hydroxyl-containing trifluoroborates. III. Suzuki-Miyaura reactions of potassium trifluoroboratohomoenolates. IV. Development of a HRMS method for organotrifluoroborates [D] . Petrillo, Daniel E. 2008

机译：功能化的有机三氟硼酸酯：合成与反应性。芳基-和杂芳基三氟硼酸酯与芳基-和杂芳基三氟甲磺酸酯的I.Suzuki-Miyaura反应。二。含羟基的三氟硼酸盐的氧化。三，三氟硼硼酸同戊烯酸钾的Suzuki-Miyaura反应。 IV。研发有机三氟硼酸盐的HRMS方法
6. Palladium-catalyzed borylation of aryl (pseudo)halides and its applications in biaryl synthesis [O] . Hong Ji, Jianghong Cai, Nana Gan, 2018

机译：钯催化的芳基（假）卤化物的硼化及其在联芳基合成中的应用
7. Palladium-catalyzed borylation of aryl mesylates and tosylates and their applications in one-pot sequential Suzuki-Miyaura biaryl synthesis [O] . Chow WK, So CM, Lau CP, 2011

机译：钯催化的芳基甲磺酸酯和甲苯磺酸酯的硼化及其在一锅顺序铃木-宫浦联芳合成中的应用

Palladium-catalyzed borylation of aryl mesylates and tosylates and their applications in one-pot sequential suzuki-miyaura biaryl synthesis

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