Tetrahedral versus planar four-coordinate carbon: A sulfonyl-substituted methandiide

Schr?ter P.; Gessner V.H.

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Tetrahedral versus planar four-coordinate carbon: A sulfonyl-substituted methandiide

机译：四面体与平面四坐标碳：磺酰基取代的乙二酰亚胺

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Flattened! The mono- and dilithiation of a sulfonyl-substituted phosphane sulfide is reported. The new dilithio methandiide features a distorted carbon environment between the typical tetrahedral and planar arrangement (see figure). This geometry results from geometrical restrictions of the donor functions and can be described by two unusual bonding modes of the lithium atoms with the sp~2-hybridized methanide carbon.

机译：展平！报道了磺酰基取代的膦硫醚的单和双锂化。新型二硫代乙met二甲醚在典型的四面体和平面排列之间具有扭曲的碳环境（见图）。这种几何形状是由于给体功能的几何限制而引起的，并且可以用锂原子与sp_2杂化的甲烷化物碳的两种不同的键合模式来描述。

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《Chemistry: A European journal》 |2012年第36期|共5页
作者
Schr?ter P.; Gessner V.H.;
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正文语种 eng
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alkali metals; carbanions; lithium; planar four-coordinate carbon; structure elucidation;

机译：碱金属;碳阴离子;锂;平面四坐标碳;结构阐明;

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1. Tetrahedral versus planar four-coordinate carbon: A sulfonyl-substituted methandiide [J] . Schr?ter P., Gessner V.H. Chemistry: A European journal . 2012,第36期

机译：四面体与平面四坐标碳：磺酰基取代的乙二酰亚胺
2. A Monomeric Dilithio Methandiide with a Distorted trans-Planar Four-Coordinate Carbon† [J] . li id=au1Oliver#x2005, J. Cooper li id=au2Ashley#x2005, J. Wooles li id=au3Jonathan McMaster Dr. li id=au4William Lewis Dr. li id=au5Alexander#x2005, Angewandte Chemie . 2010,第32期

机译：跨平面四坐标碳畸变的单体二硫代甲烷二甲胺†
3. A Monomeric Dilithio Methandiide with a Distorted trans-Planar Four-Coordinate Carbon† [J] . li id=au1Oliver#x2005, J. Cooper li id=au2Ashley#x2005, J. Wooles li id=au3Jonathan McMaster Dr. li id=au4William Lewis Dr. li id=au5Alexander#x2005, Angewandte Chemie International Edition . 2010,第32期

机译：跨平面四坐标碳畸变的单体二硫代甲烷二甲胺†
4. Automatic 3-D Crack Propagation Calculations in Industrial Components: a pure Hexahedral versus a combined Hexahedral-Tetrahedral Approach [C] . Guido Dhondt International Conference on Fracture and Damage Mechanics(FDM 2007); 20070717-19; Madeira(PT) . 2007

机译：工业组件中的自动3-D裂纹扩展计算：纯六面体与六面体-四面体组合方法
5. Experimental and computational studies of carbon sputtering with application to deposition of tetrahedrally bonded amorphous carbon films. [D] . Jonsen, Daniel Everett. 2001

机译：碳溅射在四面结合非晶碳膜沉积中的实验和计算研究。
6. Developmental capacity and pregnancy rate of tetrahedral- versus non-tetrahedral-shaped 4-cell stage human embryos [O] . T. Ebner, P. Oppelt, R. B. Mayer, 2014

机译：四面体与非四面体形状的4细胞阶段人类胚胎的发育能力和妊娠率
7. Deviations from tetrahedral four-coordinate carbon: a statistical exploration. [O] . Henry Rzepa -1

机译：偏离四面体四坐标碳：统计探索。

Tetrahedral versus planar four-coordinate carbon: A sulfonyl-substituted methandiide

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