Modular Synthesis of Linear Bis- and Tris-monodentate Fused [6]Polynorbornane-Based Ligands and their Assembly into Coordination Cages

Johnstone Mark D.; Schwarze Eike K.; Clever Guido H.; Pfeffer Frederick M.

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Modular Synthesis of Linear Bis- and Tris-monodentate Fused [6]Polynorbornane-Based Ligands and their Assembly into Coordination Cages

机译：线性双-和三-单齿熔融[6]基于聚降冰片烷的配体的模块合成及其组装成配位笼

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A modular approach has been developed for the synthesis of rigid linear di- and tritopic ligands based on a fused [6]polynorbornane scaffold. The design provides up to three sites for installing functionality, including both "ends" and a "central" position with the advantage that each region can be independently addressed during synthesis. To illustrate the utility of the approach, both pyridyl and picolyl units were incorporated to provide six new ligands, with centers and ends either matched or mismatched. Indeed, both [M2L4] cages with endohedral functionality and [M3L4] complexes were cleanly produced from these ligands with assembled structures confirmed by using H-1 NMR spectroscopy, HRMS, and molecular modelling.

机译：已经开发了一种基于熔融[6]聚降冰片烷支架的合成刚性线性二和三位配体的模块化方法。该设计最多提供三个站点来安装功能，包括“端点”和“中心”位置，其优点是在合成过程中每个区域都可以独立寻址。为了说明该方法的实用性，掺入吡啶基和吡啶基单元以提供六个新的配体，其中心和末端匹配或错配。确实，具有这些结构的[M2L4]笼和[M3L4]络合物均由具有通过H-1 NMR光谱，HRMS和分子建模证实的组装结构的这些配体干净地生产。

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《Chemistry: A European journal》 |2015年第10期|共8页
作者
Johnstone Mark D.; Schwarze Eike K.; Clever Guido H.; Pfeffer Frederick M.;
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正文语种 eng
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coordination cages; endohedral functionalization; metallosupramolecular architectures; self-assembly; supramolecular chemistry;

机译：配位笼;内膜功能化;金属超分子结构;自组装;超分子化学;

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1. Modular Synthesis of Linear Bis- and Tris-monodentate Fused [6]Polynorbornane-Based Ligands and their Assembly into Coordination Cages [J] . Johnstone Mark D., Schwarze Eike K., Clever Guido H., Chemistry: A European journal . 2015,第10期

机译：线性双-和三-单齿熔融[6]基于聚降冰片烷的配体的模块合成及其组装成配位笼
2. Imposing control on self-assembly: rational design and synthesis of a mixed-metal, mixed-ligand coordination cage containing four types of component [J] . Alexander J. Metherell, Michael D. Ward Chemical science . 2016,第2期

机译：对自组装施加控制：包含四种类型成分的混合金属混合配体协调笼的合理设计和合成
3. Imposing control on self-assembly: rational design and synthesis of a mixed-metal, mixed-ligand coordination cage containing four types of component [J] . Alexander J. Metherell, Michael D. Ward Chemical science . 2016,第2期

机译：对自组装施加控制：包含四种类型成分的混合金属混合配体协调笼的合理设计和合成
4. Synthesis and Photophysical Properties of Extended π -Conjugated System Containing Si=Si Double Bonds with a New Fused-Type Bulky Ligand [C] . Aiko Fukazawa, Yongming Li, Hayato Tsuji Symposium on Organometallic Chemistry . 2007

机译：含有Si = Si双键的延伸π-缀合系统的合成和光物理性能与新的稠合型庞大配体
5. Three Assembly Modes of Hydrothermally Synthesized Inorganic Organic Hybrid Materials: Direct Metal-Ligand Coordination, Supramolecular Chemistry, and in situ Ligand Synthesis. [D] . Cantos, Paula M. 2014

机译：水热合成无机有机杂化材料的三种组装模式：直接金属配体配位，超分子化学和原位配体合成。
6. Imposing control on self-assembly: rational design and synthesis of a mixed-metal mixed-ligand coordination cage containing four types of component [O] . Alexander J. Metherell, Michael D. Ward 2016

机译：对自组装施加控制：包含四种类型成分的混合金属混合配体协调笼的合理设计和合成
7. Inside Cover: Modular Synthesis of Linear Bis- and Tris-monodentate Fused 6Polynorbornane-Based Ligands and their Assembly into Coordination Cages (Chem. Eur. J. 10/2015) [O] . Mark D. Johnstone, Eike K. Schwarze, Guido H. Clever, 2015

机译：内部盖子：线性双型和Tris-单张的模块化合成融合6基于多诺胆甲烷的配体及其组装成协调笼（化学。欧元.J.10 / 2015）

Modular Synthesis of Linear Bis- and Tris-monodentate Fused [6]Polynorbornane-Based Ligands and their Assembly into Coordination Cages

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