meso-Pyrrole-Substituted 22-Oxacorroles: Building Blocks for the Synthesis of BODIPY-Bridged 22-Oxacorrole Dyads

Kalita Hemanta; Ravikanth Mangalampalli

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meso-Pyrrole-Substituted 22-Oxacorroles: Building Blocks for the Synthesis of BODIPY-Bridged 22-Oxacorrole Dyads

机译：内消旋吡咯取代的22-氧杂环戊烷：合成BODIPY-桥连的22-氧杂吡咯二元化合物的基础。

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Novel boron-dipyrromethene (BODIPY)-bridged 22-oxacorrole dyads, using meso-pyrrolyl 22-oxacorrole as a key synthon, have been synthesized. The reactivity of the meso-pyrrolyl group of 22-oxacorrole was exploited to synthesize the first examples of BODIPY-bridged 22-oxacorrole dyads in approximate to 40% yield. The dyads are stable and exhibited interesting spectral and electrochemical properties.

机译：合成了新型的硼-二吡咯亚甲基（BODIPY）-桥联的22-恶二唑二醛，其使用中-吡咯基22-恶二唑作为关键的合成子。利用22-恶唑基的内吡咯基团的反应性以约40％的产率合成BODIPY桥联的22-恶唑基二元组的第一个实例。二重体是稳定的，并表现出令人感兴趣的光谱和电化学性质。

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《Chemistry: A European journal》 |2015年第20期|共4页
作者
Kalita Hemanta; Ravikanth Mangalampalli;
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关键词
BODIPY; electrochemistry; energy transfer; fluorescence; meso-free meso-pyrrolyl 22-oxacorrole; meso-pyrrole group; N3O corrole-BODIPY dyad;

机译：BODIPY;电化学;能量转移;荧光;无内消旋的内吡咯基22-恶唑;中吡咯基团;N3O corrole-BODIPY dyad;

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1. meso-Pyrrole-Substituted 22-Oxacorroles: Building Blocks for the Synthesis of BODIPY-Bridged 22-Oxacorrole Dyads [J] . Kalita Hemanta, Ravikanth Mangalampalli Chemistry: A European journal . 2015,第20期

机译：内消旋吡咯取代的22-氧杂环戊烷：合成BODIPY-桥连的22-氧杂吡咯二元化合物的基础。
2. Synthesis of meso-Pyrrole-Substituted 22-Oxacorroles by a “3+2” Approach [J] . Hemanta Kalita, Dhrubajyoti Kalita, Way-Zen Lee, Chemistry: A European journal . 2014,第33期

机译：通过“ 3 + 2”方法合成内消旋吡咯取代的22-氧戊酸酯
3. Synthesis of mono-functionalized core-modified expanded porphyrin building blocks and covalently linked expanded porphyrin dyads [J] . Pareek Y., Ravikanth M. European journal of organic chemistry . 2011,第27期

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meso-Pyrrole-Substituted 22-Oxacorroles: Building Blocks for the Synthesis of BODIPY-Bridged 22-Oxacorrole Dyads

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