Synthesis and Coordination Chemistry of Iminophosphanes

van Dijk Tom; Burck Sebastian; Rosenthal Amos J.; Nieger Martin; Ehlers Andreas W.; Slootweg J. Chris; Lammertsma Koop

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Synthesis and Coordination Chemistry of Iminophosphanes

机译：氨基膦的合成与配位化学

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Iminophosphanes are a new group of 1,3-P,N-ligands, readily obtainable from secondary phosphanes and nitrilium ions, having a tunable N-donor site by means of varying the imine substituents. These ligands give, in high yields, monodentate gold complexes and bidentate rhodium and iridium complexes. Crystal structures are reported for both the ligands and the complexes.

机译：亚氨基膦是一组新的1，3-P，N-配体，可容易地从仲膦和腈离子获得，其通过改变亚胺取代基具有可调的N-供体位点。这些配体以高收率得到单齿金配合物和二齿铑和铱配合物。报道了配体和配合物的晶体结构。

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来源
《Chemistry: A European journal》 |2015年第26期|共4页
作者
van Dijk Tom; Burck Sebastian; Rosenthal Amos J.; Nieger Martin; Ehlers Andreas W.; Slootweg J. Chris; Lammertsma Koop;
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正文语种 eng
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关键词
ligand design; coordination modes; synthetic methods; N; P ligands; density functional calculations;

机译：配体设计;配位方式;合成方法;N;P配体;密度泛函计算;

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1. Synthesis and Coordination Chemistry of Iminophosphanes [J] . van Dijk Tom, Burck Sebastian, Rosenthal Amos J., Chemistry: A European journal . 2015,第26期

机译：氨基膦的合成与配位化学
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7. Synthesis and coordination chemistry of ligands for supramolecular chemistry and sensing applications [O] . Clayton Hayley J 2008

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Synthesis and Coordination Chemistry of Iminophosphanes

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