Intramolecular Communication in Anionic Oxidized Phosphanes through a Chelated Proton

Popescu A. R.; Rojo I.; Teixidor F.; Sillanpaa R.; Vinas C.

首页> 外文期刊>Chemistry: A European journal >Intramolecular Communication in Anionic Oxidized Phosphanes through a Chelated Proton

【24h】

Intramolecular Communication in Anionic Oxidized Phosphanes through a Chelated Proton

机译：通过螯合质子在阴离子氧化磷中的分子内通讯

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Oxidation of the 1,2-(PR2)(2)-1,2-closo-C2B10H10 (R=Ph, iPr) platform with hydrogen peroxide in acetone is a two-step procedure in which partial deboronation of the closo cluster and oxidation of the phosphorus atoms occur. Based on NMR spectroscopic and kinetic data, we demonstrate that the phosphorus atoms are oxidized in the first step, followed by cluster deboronation. DFT calculations and natural-bond orbital (NBO) analysis were used to obtain insight into the electronic structures of diphosphane ortho-carborane derivatives.

机译：在丙酮中用过氧化氢氧化1,2-（PR2）（2）-1,2-closo-C2B10H10（R = Ph，iPr）平台是一个两步过程，其中closo簇的部分脱硼和氧化发生了磷原子。基于NMR光谱和动力学数据，我们证明了第一步中的磷原子被氧化，然后发生簇脱硼。使用DFT计算和自然键轨道（NBO）分析来深入了解二膦正碳烷衍生物的电子结构。

著录项

来源
《Chemistry: A European journal》 |2015年第23期|共13页
作者
Popescu A. R.; Rojo I.; Teixidor F.; Sillanpaa R.; Vinas C.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词
carboranes; carboranylphosphanes; hydrogen bonds; oxidation; phosphorus;

机译：碳硼烷;碳烷基膦;氢键;氧化;磷;

相似文献

外文文献
中文文献
专利

1. Intramolecular Communication in Anionic Oxidized Phosphanes through a Chelated Proton [J] . Popescu A. R., Rojo I., Teixidor F., Chemistry: A European journal . 2015,第23期

机译：通过螯合质子在阴离子氧化磷中的分子内通讯
2. Convenient Synthesis of New Anionic Water-Soluble Phosphanes and Applications in Inter-and Intramolecular Heck Reactions [J] . Remi Amengual, Emilie Genin, Veronique Michelet, Advanced synthesis & catalysis . 2002,第3a4期

机译：新型阴离子水溶性膦的简便合成及其在分子间和分子内的Heck反应中的应用
3. Car-Parrinello and path integral molecular dynamics study of the intramolecular hydrogen bond in the novel class of anionic H-chelates: 6-Nitro-2,3-dipyrrol-2-ylquinoxaline anion [J] . Durlak P, Latajka Z Chemical Physics Letters . 2009,第4a6期

机译：Car-Parrinello和路径积分分子动力学研究的新型阴离子H-螯合物：6-硝基-2,3-二吡咯-2-基喹喔啉阴离子中的分子内氢键
4. Conjugated Oligomers Forming an Intramolecular Hydrogen Bonding: Twisted Conformation and Excited-State Intramolecular Proton Transfer [C] . Koji Takagi, Shin-ichi Matsuoka, Masato Suzuki World multi-conference on systemics, cybernetics and informatics;WMSCI 2008;ISAS;International conference on Information systems analysis and synthesis;International symposium on management, engineering and informatics;MEI 2008 . 2008

机译：共轭低聚物形成分子内氢键：扭曲构象和激发态分子内质子转移。
5. Interactions of anionic surfactants with lead, protons, and naphthalene in aqueous and soil systems: An experimental and modeling study. [D] . Huang, Chih. 1999

机译：阴离子表面活性剂与水，土壤系统中铅，质子和萘的相互作用：一项实验和模型研究。
6. Reactions of an anionic chelate phosphane/borata-alkene ligand with Rh(nbd)Cl [O] . Kohei Watanabe, Atsushi Ueno, Xin Tao, 2020

机译：阴离子螯合膦/硼酰烯配体与RH（NBD）CL的反应
7. Reactions of an anionic chelate phosphane/borata-alkene ligand with Rh(nbd)Cl2, Rh(CO)2Cl2 and Ir(cod)Cl2 [O] . Kohei Watanabe, Atsushi Ueno, Xin Tao, 2020

机译：阴离子螯合膦/硼酰胺 - 烯烃配体用RH（NBD）Cl 2，RH（CO）2CL 2和IR（COD）CL 2的反应
8. Beneficiation of Western Mesabi Range Oxidized Taconites: A Comparison of the Anionic and Cationic Flotation Systems and an Evaluation of Potential Iron Ore Reserves [R] . Jacobs, H. D. 1981

机译：Western mesabi系列氧化Taconites的选矿：阴离子和阳离子浮选系统的比较以及潜在铁矿石储量的评价

Intramolecular Communication in Anionic Oxidized Phosphanes through a Chelated Proton

摘要

著录项

相似文献

相关主题

期刊订阅