A Straightforward Approach to Tetrahydroindolo[3,2-b]carbazoles and 1-Indolyltetrahydrocarbazoles through [3+3] Cyclodimerization of Indole-Derived Cyclopropanes

Ivanova Olga A.; Budynina Ekaterina M.; Khrustalev Victor N.; Skvortsov Dmitriy A.; Trushkov Igor V.; Melnikov Mikhail Ya.

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A Straightforward Approach to Tetrahydroindolo[3,2-b]carbazoles and 1-Indolyltetrahydrocarbazoles through [3+3] Cyclodimerization of Indole-Derived Cyclopropanes

机译：通过吲哚衍生的环丙烷的[3 + 3]环二聚反应制备四氢吲哚并[3,2-b]咔唑和1-吲哚基四氢咔唑的简便方法

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A rapid new approach to produce biologically relevant bisindoles, namely indolyltetrahydrocarbazoles and indolo[3,2-b]carbazoles, has been developed, based on the Ga(OTf)(3)-catalyzed [3+3] cyclodimerization of indole-derived donor-acceptor cyclopropanes. Chemoselectivity of the process depends on the location of the three-membered ring at the indole core.

机译：基于由吲哚衍生的供体的Ga（OTf）（3）催化的[3 + 3]环二聚，已开发出一种快速的新方法来生产生物学相关的双吲哚，即吲哚基四氢咔唑和吲哚[3,2-b]咔唑-受体环丙烷。该过程的化学选择性取决于三元环在吲哚核上的位置。

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《Chemistry: A European journal》 |2016年第4期|共5页
作者
Ivanova Olga A.; Budynina Ekaterina M.; Khrustalev Victor N.; Skvortsov Dmitriy A.; Trushkov Igor V.; Melnikov Mikhail Ya.;
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正文语种 eng
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关键词
cyclopropanes; dimerization; domino reactions; indoles; Lewis acids;

机译：环丙烷;二聚;多米诺反应;吲哚;路易斯酸;

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1. A Straightforward Approach to Tetrahydroindolo[3,2-b]carbazoles and 1-Indolyltetrahydrocarbazoles through [3+3] Cyclodimerization of Indole-Derived Cyclopropanes [J] . Ivanova Olga A., Budynina Ekaterina M., Khrustalev Victor N., Chemistry: A European journal . 2016,第4期

机译：通过吲哚衍生的环丙烷的[3 + 3]环二聚反应制备四氢吲哚并[3,2-b]咔唑和1-吲哚基四氢咔唑的简便方法
2. Shortcut Approach to Cyclopenta[b]indoles by [3+2] Cyclodimerization of Indole-Derived Cyclopropanes [J] . Olga A. Ivanova, Ekaterina M. Budynina, Dmitriy A. Skvortsov, Synlett . 2014,第16期

机译：吲哚衍生的环丙烷的[3 + 2]环二聚反应形成环戊[b]吲哚的捷径
3. Concise approach to pyrrolizino[1,2-b]indoles from indole-derived donor-acceptor cyclopropanes [J] . Villemson Elena V., Budynina Ekaterina M., Ivanova Olga A., RSC Advances . 2016,第66期

机译：简洁的吲哚衍生的供体 - 受体环丙烷的Pyrolizino [1,2-B]吲哚的方法
4. A Straightforward Approach to Tetrahydroindolo3,2-b carbazoles and 1-Indolyltetrahydrocarbazoles through 3+3 Cyclodimerization of Indole-Derived Cyclopropanes [O] . Olga A. Ivanova, Ekaterina M. Budynina, Victor N. Khrustalev, 2015

机译：通过3 + 3吲哚衍生的环丙烷的3 + 3环二聚体的吲哚衍生的环丙烷的环肼3,2-B咔唑和1-吲哚基二碳唑并进行直接的

A Straightforward Approach to Tetrahydroindolo[3,2-b]carbazoles and 1-Indolyltetrahydrocarbazoles through [3+3] Cyclodimerization of Indole-Derived Cyclopropanes

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