Suppression of Photocyclization: Stabilization of an Aggregation-Induced Tetraaryldistyrylbenzene Emitter

Freudenberg Jan; Rominger Frank; Bunz Uwe H. F.

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Suppression of Photocyclization: Stabilization of an Aggregation-Induced Tetraaryldistyrylbenzene Emitter

机译：光环化的抑制：聚集诱导的四芳基二苯乙烯基苯发射体的稳定化。

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The synthesis of 2,3,5,6-tetrakis(2,6-difluorophenyl)di(styryl)benzene by using a conventional synthetic sequence, including Diels-Alder and Horner reactions is reported. The target is an effective aggregation-induced emitter. It is photostable with respect to electrocyclization, due to the presence of the fluorine substituents. This compound undergoes photochemical trans/cis isomerization of its styryl double bonds.

机译：据报道，通过包括Diels-Alder和Horner反应在内的常规合成顺序，合成了2,3,5,6-四（2,6-二氟苯基）二（苯乙烯基）苯。目标是有效的聚集诱导的发射体。由于存在氟取代基，因此对于电环化它是光稳定的。该化合物的苯乙烯基双键经历光化学反式/顺式异构化。

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来源
《Chemistry: A European journal》 |2016年第26期|共5页
作者
Freudenberg Jan; Rominger Frank; Bunz Uwe H. F.;
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正文语种 eng
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关键词
aggregation-induced emission; distyrylbenzene; electrocyclization; fluorescence; photochemistry;

机译：聚集诱导发射;二苯乙烯基苯;电环化;荧光;光化学;

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1. Suppression of Photocyclization: Stabilization of an Aggregation-Induced Tetraaryldistyrylbenzene Emitter [J] . Freudenberg Jan, Rominger Frank, Bunz Uwe H. F. Chemistry: A European journal . 2016,第26期

机译：光环化的抑制：聚集诱导的四芳基二苯乙烯基苯发射体的稳定化。
2. Spiro-Functionalized Diphenylethenes: Suppression of a Reversible Photocyclization Contributes to the Aggregation-Induced Emission Effect [J] . Zhou Zhibiao, Xie Sheng, Chen Xian, Journal of the American Chemical Society . 2019,第25期

机译：螺功能化的二苯乙烯：抑制可逆的光环化有助于聚集诱导的排放效应。
3. Spiro-Functionalized Diphenylethenes: Suppression of a Reversible Photocyclization Contributes to the Aggregation-Induced Emission Effect [J] . Zhou Zhibiao, Xie Sheng, Chen Xian, Journal of the American Chemical Society . 2019,第25期

机译：螺旋官能化二苯基乙烯：抑制可逆光循环有助于聚集诱导的发射效果
4. Blue aggregation-induced emission molecules for non-doped organic light-emitting diodes [C] . Dain Lo, Yu-Chien Hsu, Chih-Hao Chang, . 2017

机译：用于非掺杂有机发光二极管的蓝色聚集诱导的发射分子
5. Native oxidation of aluminum-bearing III-V semiconductors with applications to edge- and surface-emitting lasers and to the stabilization of light emitting diodes. [D] . Richard, Timothy Allen. 1995

机译：含铝III-V半导体的自然氧化，可应用于边缘发射和表面发射激光器以及发光二极管的稳定化。
6. Mulifunctional Dendritic Emitter: Aggregation-Induced Emission Enhanced Thermally Activated Delayed Fluorescent Material for Solution-Processed Multilayered Organic Light-Emitting Diodes [O] . Kenichi Matsuoka, Ken Albrecht, Kimihisa Yamamoto, -1

机译：多功能树突状发射体：用于溶液处理的多层有机发光二极管的聚集诱导发射增强的热活化延迟荧光材料。
7. Spiro-Functionalized Diphenylethenes: Suppression of a Reversible Photocyclization Contributes to the Aggregation-Induced Emission Effect [O] . -1

机译：螺旋官能化二苯基乙烯：抑制可逆光循环有助于聚集诱导的发射效果

Suppression of Photocyclization: Stabilization of an Aggregation-Induced Tetraaryldistyrylbenzene Emitter

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