Hydro-aza-(C59N)fullerenes: Formation Mechanism and Hydrogen Substitution

Eigler Regina; Heinemann Frank W.; Hirsch Andreas

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Hydro-aza-(C59N)fullerenes: Formation Mechanism and Hydrogen Substitution

机译：氢氮杂（C59N）富勒烯：形成机理和氢取代

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Azafullerenes are as yet the only synthetically available heterofullerenes. Herein, we present plausible reaction pathways towards pentaaryl azafullerenes, focusing on the reactivity of hydro-azafullerene intermediates and their regiochemistry. The X-ray structure of a -hydro-tetraaryl adduct is presented for the first time. The reactivity of dihydro-azafullerene adducts is demonstrated here through H-abstraction in mass spectrometric experiments. Moreover, hydride abstraction and subsequent hydroxylation is possible, as well as deprotonation followed by alkylation.

机译：氮杂富勒烯是迄今为止唯一可合成获得的杂富勒烯。在这里，我们提出对五芳基氮杂富勒烯的合理反应途径，重点是氢氮杂富勒烯中间体的反应性及其区域化学。首次提出了-氢-四芳基加合物的X射线结构。二氢氮杂富勒烯加合物的反应性在质谱实验中通过H萃取得到了证实。此外，氢化物提取和随后的羟基化以及去质子化然后烷基化是可能的。

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《Chemistry: A European journal》 |2016年第38期|共7页
作者
Eigler Regina; Heinemann Frank W.; Hirsch Andreas;
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正文语种 eng
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azafullerene; deprotonation; hydro-fullerene; reaction mechanisms; regioselectivity;

机译：氮杂富勒烯;去质子化;氢富勒烯;反应机理;区域选择性;

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1. Hydro-aza-(C59N)fullerenes: Formation Mechanism and Hydrogen Substitution [J] . Eigler Regina, Heinemann Frank W., Hirsch Andreas Chemistry: A European journal . 2016,第38期

机译：氢氮杂（C59N）富勒烯：形成机理和氢取代
2. Formation mechanism and structural and electronic properties of metal-substituted fullerenes C69M (M = Co, Rh, and Ir) - art. no. 043201 [J] . Ding CG., Han RS., Wang KL., Physical Review, A. Atomic, molecular, and optical physics . 2001,第4期

机译：金属取代的富勒烯C69M（M = Co，Rh和Ir）的形成机理以及结构和电子性质-艺术。没有。 043201
3. Mechanism of Formation of N-oxide Substituted Benztriazols in the Reaction of Liquid Phase Catalytic Hydrogenation of 2-Nitro-2`-Hydroxy-5`-Methylazobenzene [J] . Atef S. ALzaydien Journal of Applied Sciences . 2004,第1期

机译：2-硝基-2`-羟基-5`-甲基偶氮苯液相催化加氢反应中N-氧化物取代的苯并三唑的形成机理
4. The Peculiarities of Hydrogenation of Fullerene Molecules C_(60) and Their Transformation [C] . Dmitry V. Schur, Svetlana Yu. Zaginaichenko, T. Nejat Veziroglu, NATO advanced research workshop on the Black Sea: strategy for addressing its energy resource development and hydrogen energy problems . 2013

机译：富勒烯分子C_（60）氢化的特性及其转化
5. Functional consequences of substitutions for the prosthetic group of the inner lipoyl domain of dihydrolipoyl acetyltransferase and the inner lipoyl domain's mechanism of activation of pyruvate dehydrogenase kinase isoform 3 [D] . Peng, Tao. 2001

机译：取代二氢脂酰乙酰基转移酶的内部脂酰结构域的修复基的功能性后果和内部脂酰结构域的丙酮酸脱氢酶激酶同工型3的激活机制
6. Conformational Analysis of the Supramolecular Complexationof Diaryl-Substituted Tetrathiafulvalene Vinylogues with Fullerenes [O] . Ahmad I. Alrawashdeh, *, Yuming Zhao, 2019

机译：超分子络合物的构象分析二芳基取代的四硫富瓦烯乙烯基化合物与富勒烯的合成
7. Mechanism of Formation of N-oxide Substituted Benztriazols in the Reaction of Liquid Phase Catalytic Hydrogenation of 2-Nitro-2`-Hydroxy-5`-Methylazobenzene [O] . Atef S. ALzaydien 2003

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8. Cyclocarbon Coalescence: Mechanisms for Tailormade Fullerene Formation [R] . McElvany, S. W., Ross, M. M., Goroff, N. S., 1993

机译：碳环聚结：Tailormade富勒烯形成的机制

Hydro-aza-(C59N)fullerenes: Formation Mechanism and Hydrogen Substitution

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