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Dehydration reactions and microanostructures in experimentally-deformed serpentmites

机译:实验变形蛇形虫的脱水反应和微观/纳米结构

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High-T torsion experiments on lizardite + chrysotile serpentinites produced mineralogical and micro/ nanostructural changes, with important implications in rheological properties. High-resolution TEM showed that specimens underwent ductile [by microkinking and (001) interlayer glide] and brittle deformation (by microfractur-ing), together with dehydration and break-down reactions. Lizardite is affected by polytypic disorder and microkinking [kink axial planes at high angle with respect to (001) planes], that were not present in the initial ordered lT-lizardite. Chrysotile fibres are deformed, resulting in elliptical cross-sections, with strong loss of interlayer cohesion. Both lizardite and chrysotile break down to a fine intergrowth of olivine (up to 200 nm), talc (up to 30 nm) and poorly-crystalline material. Lizardite-out reaction preferentially occurs at kink axial planes, representing sites of preferential strain and enhanced reactivity; conversely, chrysotile break-down is a bulk process, resulting in large healed olivine aggregates, up to micrometric in size. Overall observations suggest that dehydration and breakdown reactions are more advanced in chrysotile than in lizardite.
机译:蜥蜴石+温石棉蛇纹石的高T扭转实验产生了矿物学和微观/纳米结构的变化,对流变性质具有重要意义。高分辨率TEM显示,标本经历了延性[通过微扭结和(001)层间滑移]和脆性变形(通过微断裂),以及脱水和分解反应。蜥蜴石受多型性紊乱和微扭折[相对于(001)平面成高角度的扭折轴向平面)的影响,这在最初的有序IT蜥蜴石中不存在。温石棉纤维变形,形成椭圆形横截面,层间内聚力大大降低。蜥蜴石和温石棉都分解为橄榄石(最大200 nm),滑石(最大30 nm)和结晶度较差的材料的良好共生体。蜥蜴石出反应优先发生在扭结轴向平面,代表优先应变和增强反应性的位点。相反,温石棉分解是一个整体过程,导致愈合的橄榄石聚集体大到微米大小。总体观察结果表明,温石棉中的脱水和分解反应比蜥蜴石中的脱水和分解反应更先进。

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