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Blue light emitting self-healable graphene quantum dot embedded hydrogels

机译:蓝光发射自修复石墨烯量子点嵌入式水凝胶

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摘要

Graphene quantum dots (GQDs) embedded into synthesized Amoc (N-anthracenemethyloxycarbonyl) capped aromatic amino acid based units in completely aqueous environments exhibit blue light emitting self-healable hydrogels. These Amoc amino acid/GQD assemblies in hydrogel states encourage blue light emission under UV irradiation at a wavelength of 365 nm. The quenching in emission spectra reveals strong pi-pi stacking interactions within aromatic GQDs and Amoc-amino acids. Fluorescence spectra confirm the stabilization of GQDs on fibrils and electron microscopy images depict the distribution of GQDs on the nanofibrillar 3D networks. The self-healing properties and thixotropic nature of the hydrogels can be tuned by the inclusion of GQDs.
机译:在完全水性环境中,嵌入合成的Amoc(N-蒽甲基甲氧羰基)封端的芳族氨基酸基单元中的石墨烯量子点(GQD)呈现出蓝色发光的自修复水凝胶。这些处于水凝胶状态的Amoc氨基酸/ GQD组件可在365 nm波长的紫外线照射下促进蓝光发射。发射光谱的猝灭揭示了芳族GQD和Amoc-氨基酸之间强烈的pi-pi堆积相互作用。荧光光谱证实了GQD在原纤维上的稳定性,电子显微镜图像描绘了GQD在纳米原纤维3D网络上的分布。可以通过包含GQD来调整水凝胶的自愈特性和触变性。

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