Catalytic enantioselective oxa-hetero-Diels-Alder reactions of enones with aryl trifluoromethyl ketones

Zhang Dongxin; Tanaka Fujie

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Catalytic enantioselective oxa-hetero-Diels-Alder reactions of enones with aryl trifluoromethyl ketones

机译：烯酮与芳基三氟甲基酮的催化对映选择性氧杂杂Diels-Alder反应

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The development of oxa-hetero-Diels-Alder reactions of enones with aryl trifluoromethyl ketones to afford tetrahydropyranones bearing trifluoromethyl-substituted tetrasubstituted carbon centers is reported. The reactions were catalyzed by an amine-based catalyst system and afforded the products with er values up to 97 : 3.

机译：报道了烯酮与芳基三氟甲基酮的氧杂杂Diels-Alder反应的发展，得到了带有三氟甲基取代的四取代碳中心的四氢吡喃酮。通过胺基催化剂体系催化反应，得到的er值高达97：3。

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《RSC Advances》 |2016年第66期|共4页
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Zhang Dongxin; Tanaka Fujie;
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1. Catalytic enantioselective oxa-hetero-Diels-Alder reactions of enones with aryl trifluoromethyl ketones [J] . Zhang Dongxin, Tanaka Fujie RSC Advances . 2016,第66期

机译：烯酮与芳基三氟甲基酮的催化对映选择性氧杂杂Diels-Alder反应
2. Enantioselective Synthesis of Tertiary Trifluoromethyl Carbinols by Vinylogous Aldol Reaction of 3-Methylcyclohex-2-en-1-one with (Het)aryl Trifluoromethyl Ketones [J] . Chen Fenfen, Chang Zhixin, Paidamoyo Chigumbu, Synlett . 2019,第2期

机译：用（HET）芳基三氟甲基酮（HET）芳基三氟甲基-2-烯-1-on的乙烯基醛醇反应对三氟甲基猪肉的映选择性合成
3. Aldol Reactions of Ketone Donors with Aryl Trifluoromethyl Ketone Acceptors Catalyzed by 1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU) for Concise Access to Aryl- and Trifluoromethyl-Substituted Tertiary Alcohols [J] . Zhang Dongxin, Tanaka Fujie Advanced synthesis & catalysis . 2015,第16a17期

机译：1,8-二氮杂双环[5.4.0]十一碳-7-烯（DBU）催化的酮供体与芳基三氟甲基酮受体的醛醇缩合反应，用于简捷地获得芳基和三氟甲基取代的叔醇
4. Halogenotin Hydride Catalyzed Reductive Aldol Reaction of Enones with Ketones [C] . Kumiko Sakabe Scheme, Ikuya Shibata Symposium on Organometallic Chemistry . 2008

机译：卤素蛋白氢化物用酮催化烯酮的还原醛醇反应
5. Catalytic Enantioselective Additions of Allyl Moieties to α-Halomethyl Ketones, Trifluoromethyl Substituted Nh-Ketimines, and Nitriles [D] . Fager, Diana C. 2020

机译：烯丙基部分催化对α-卤代甲基酮，三氟甲基取代的NH-酮酰亚胺和腈
6. Enantioselective Synthesis of All-Carbon Quaternary Stereogenic Centers by Catalytic Asymmetric Conjugate Additions of Alkyl and Aryl Aluminum Reagents to Five- Six- and Seven-Membered-Ring β-Substituted Cyclic Enones [O] . Tricia L. May, M. Kevin Brown, Amir H. Hoveyda -1

机译：烷基和芳烃铝试剂催化不对称共轭加成五元六元和七元环β-取代的环烯酮的全碳四元立体中心的对映选择性合成
7. Direct, Catalytic Enantioselective Nitroaldol (Henry) Reaction of Trifluoromethyl Ketones: An Asymmetric Entry to a-Trifluoromethyl-Substituted Quaternary Carbons [O] . -1

机译：三氟甲基酮的直接，催化对映选择性硝基甲醇（亨利）反应：对α-三氟甲基取代的季碳的不对称进入

Catalytic enantioselective oxa-hetero-Diels-Alder reactions of enones with aryl trifluoromethyl ketones

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