Synthesis of [{2,6-(Me2NCH2)(2)C6H3}Sn(OH)O](6): an N -  Sn Coordinated Stannonic Acid

Bouska Marek; Dostal Libor; Jirasko Robert; Ruzicka Ales; Jambor Roman

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Synthesis of [{2,6-(Me2NCH2)(2)C6H3}Sn(OH)O](6): an N - Sn Coordinated Stannonic Acid

机译：[{2,6-（Me2NCH2）（2）C6H3} Sn（OH）O]（6）的合成：N-> Sn配位的锡酸

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The discovery of the possible hydrolytic mechanism of the monoorganotin (IV) compound RSn (H2O) (O2CCF3)(3) (2) resulted in the preparation of the first intramolecularly coordinated stannonic acid, [RSn(OH)O](6) (3) (R is the N,C,N-pincer ligand [2,6-(Me2NCH2)(2)C6H3](-)). The presence of N -> Sn coordination prevents the formation of additional Sn-O interactions and results in the stabilization of the unique centrosymmetric {Sn6O12} core in 3.

机译：单有机锡（IV）化合物RSn（H2O）（O2CCF3）（3）（2）可能的水解机理的发现导致制备了第一个分子内配位的锡酸[RSn（OH）O]（6）（ 3）（R是N，C，N-钳位配体[2,6-（Me2NCH2）（2）C6H3]（-））。 N-> Sn配位的存在阻止了额外的Sn-O相互作用的形成，并导致3中唯一的中心对称{Sn6O12}核的稳定性。

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《Organometallics》 |2009年第15期|共4页
作者
Bouska Marek; Dostal Libor; Jirasko Robert; Ruzicka Ales; Jambor Roman;
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正文语种 eng
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NMR CHARACTERIZATION; SOLID-STATE; TRANSESTERIFICATION; BOND; REACTIVITY; CATALYSTS; OXIDE;

机译：核磁共振;表征;固态;酯交换;键合;反应性;催化剂;氧化物;

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1. Synthesis of [{2,6-(Me2NCH2)(2)C6H3}Sn(OH)O](6): an N - Sn Coordinated Stannonic Acid [J] . Bouska Marek, Dostal Libor, Jirasko Robert, Organometallics . 2009,第15期

机译：[{2,6-（Me2NCH2）（2）C6H3} Sn（OH）O]（6）的合成：N-> Sn配位的锡酸
2. Synthesis of intramolecularly coordinated heteroleptic diorganotellurides and diorganotelluroxides: Isolation of monomeric diorganotelluroxide [{2,6-(Me2NCH2)(2)C6H3}(2)TeO] and diorganohydroxytelluronium chloride [{2,6-(Me2NCH2)(2)C6H3}(2)Te(OH)]Cl [J] . Gupta Anand, Deka Rajesh, Raju Saravanan, Journal of Organometallic Chemistry . 2019,第期

机译：分子内协调的异致硫化脲和硫磷酸酯的合成：单体DirgonoTelluxide的分离[{2,6-（ME2NCH2）（2）C6H3}（2）TEO]和Diorgorohoydroxylarium氯酰氯[{2,6-（ME2NCH2）（2）C6H3}（ 2）TE（OH）] CL
3. [{2,6-(Me2NCH2)(2)C6H3(H2O)Sn}W(CO)(5)]+CB11H12-: Aqua Complex of a Transition-Metal-Bound Organotin(II) Cation versus an Ammonium-Type Structure [J] . Jambor R, Kasna B, Koller SG, European journal of inorganic chemistry . 2010,第6期

机译：[{2,6-（Me2NCH2）（2）C6H3（H2O）Sn} W（CO）（5）] + CB11H12-：过渡金属结合的有机锡（II）阳离子与铵型结构的水络合物
4. Synthesis of Dimethyl Carbonate from Carbon Dioxide and Methanol Catalyzed by the Sn-Acid Combination [C] . Kazufumi Kohno, Jun-Chul Choi, Hiroyuki Yasuda Symposium on Organometallic Chemistry . 2006

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5. Controlled Synthesis of Pt-Sn/Al2O3 Catalysts and Their Application in the Hydrodeoxygenation of Bio-Based Succinic Acid [D] . Howe, Patrick Michael. 2019

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6. Design Synthesis and Biological Activity of Novel Triazole Amino Acids Used To Probe Binding Interactions Between Ligand and Neutral Amino Acid Transport Protein SN1 [O] . Mariusz Gajewski, Ben Seaver, C. Sean Esslinger -1

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7. Synthesis of the Five-Coordinate Ruthenium (II) Complexes [(PCP)Ru(CO)(L)][BAr'4] {PCP = 2,6-(CH2PtBu2)2 C6H3, BAr'4 = 3,5-(CF3)2C6H3, L= ɳ1-CICH2CI, ɳ 1-N2, or μ-Cl-Ru(PCP)(CO)}: Reactions with Phenyldiazomethane and Phenylacetylene [O] . Zhang, Jubo, Barakat, Khaldoon A., Cundari, Thomas R., 1964-, 2005

机译：五配位钌（II）配合物的合成[（pCp）Ru（CO）（L）] [Bar'4] {pCp = 2,6-（CH2ptBu2）2 C6H3，Bar'4 = 3,5-（ CF3）2C6H3，L =ɳ1-CICH2CI，ɳ1-N2或μ-Cl-Ru（pCp）（CO）}：与苯基重氮甲烷和苯乙炔的反应
8. Photochemical Synthesis and Electron Spin Resonance Characterisation of Stable Trivalent Metal Alkyls (Si, GE, SN) and Amides (Ge and Sn) of Group IV Elements. [R] . Cotton, J. D., Cundy, C. S., Harris, D. H., 1974

机译：IV族元素的稳定三价金属烷基（si，GE，sN）和酰胺（Ge和sn）的光化学合成和电子自旋共振特性。

Synthesis of [{2,6-(Me2NCH2)(2)C6H3}Sn(OH)O](6): an N - Sn Coordinated Stannonic Acid

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