Synthesis and reactivity of five-membered palladalactones from arylallenes and carbon dioxide: Relevance to catalytic lactone synthesis

Choi J.-C.; Shiraishi K.; Takenaka Y.; Yasuda H.; Sakakura T.

首页> 外文期刊>Organometallics >Synthesis and reactivity of five-membered palladalactones from arylallenes and carbon dioxide: Relevance to catalytic lactone synthesis

【24h】

Synthesis and reactivity of five-membered palladalactones from arylallenes and carbon dioxide: Relevance to catalytic lactone synthesis

机译：由芳基亚丙基和二氧化碳合成五元新戊内酯与反应：与催化内酯合成有关

获取原文

获取原文并翻译 | 示例

获取外文期刊封面封底 >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A bis(tri-n-butylphosphine)palladium ((nBu_3P)_2Pd) complex was shown to catalyze the cyclization of arylallenes with carbon dioxide to yield six-membered lactones. The stoichiometric reaction of a (Me_3P)_2Pd complex with 1 equiv of arylallenes, followed by treatment with CO_2, resulted in the formation of five-membered palladalactones, the structures of which were fully characterized by X-ray crystallography, NMR, IR, HRMS, and elemental analysis.

机译：已显示双（三正丁基膦）钯（（nBu_3P）_2Pd）配合物可催化芳基烯与二氧化碳的环化反应，生成六元内酯。（Me_3P）_2Pd配合物与1当量的芳基烯烯的化学计量反应，然后用CO_2处理，形成了五元的戊内酯，其结构通过X射线晶体学，NMR，IR，HRMS进行了完全表征以及元素分析。

著录项

来源
《Organometallics》 |2013年第11期|共4页
作者
Choi J.-C.; Shiraishi K.; Takenaka Y.; Yasuda H.; Sakakura T.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词
Synthesis; reactivity; five-membered;

机译：合成;反应性;五元;

相似文献

外文文献
中文文献
专利

1. Synthesis and reactivity of five-membered palladalactones from arylallenes and carbon dioxide: Relevance to catalytic lactone synthesis [J] . Choi J.-C., Shiraishi K., Takenaka Y., Organometallics . 2013,第11期

机译：由芳基亚丙基和二氧化碳合成五元新戊内酯与反应：与催化内酯合成有关
2. Synthesis of 1',3'-dioxolan-2'-one by the reaction of steroidal oxiranes with carbon dioxide: Synthesis of five-membered cis cyclic carbonates [J] . Shamsuzzaman, Baqi K.A.A.A. Synthetic Communications . 2010,第13a15期

机译：甾体环氧乙烷与二氧化碳反应合成1'，3'-二氧戊环-2'-one：五元顺式环状碳酸酯的合成
3. One-Pot Synthesis of alpha,beta-Unsaturated gamma-Lactones and Lactams via a Sequential trans-Hydroalumination and Catalytic Carboxylation of Propargyl Alcohols and Amines with Carbon Dioxide [J] . Yoo Woo-Jin, Chen Wenlong, Nguyen Thanh V. Q., Organic letters . 2020,第6期

机译：通过序贯的反式氢透射液和催化羧化与二氧化碳的丙氨酸和胺的催化羧化α，β-不饱和γ-乳酰胺和内酰胺的单壶合成
4. Synthesis and Reactivity of Five-Membered Palladalactone from Arylallenes and Carbon Dioxide Relevant to Catalytic Lactone Synthesis [C] . Kouichi Shiraishi, Jun-Chul Choi, Toshiyasu Sakakura Symposium on Organometallic Chemistry . 2003

机译：五元钯丙烯酸钯和二氧化碳相关催化内酯合成的合成与反应性
5. Reactivity of carbon dioxide with organosamarium compounds and the synthesis and reactivity of solvent free organolanthanide metallocene cations. [D] . Seibel, Christopher Alan. 1998

机译：二氧化碳与有机sa化合物的反应性以及无溶剂的有机镧系金属茂阳离子的合成和反应性。
6. Immobilizing Polyether Imidazole Ionic Liquids on ZSM-5 Zeolite for the Catalytic Synthesis of Propylene Carbonate from Carbon Dioxide [O] . Liying Guo, Xianchao Jin, Xin Wang, 2018

机译：在ZSM-5沸石上固定化聚醚咪唑离子液体用于二氧化碳催化合成碳酸丙烯酯
7. Ethanol Synthesis by Catalytic Hydrogenation of Carbon Dioxide over Promoted Rhodium Catalysts. I. The Effect of Additives on Ethanol Synthesis by Catalytic Hydrogenation of Carbon Dioxide over Silica Supported Rhodium Catalysts. [O] . Hitoshi KUSAMA, Kazuhiro SAYAMA, Kiyomi OKABE, 1995

机译：通过促进铑催化剂的二氧化碳催化氢化乙醇合成。 I.二氧化硅上二氧化碳催化氢化添加剂对乙醇合成的作用。
8. Carbon Dioxide Reduction via Homogeneous Catalytic Synthesis and Hydrogenation of N,N-Dimethylformamide [R] . Schreiner, S., Yu, J. Y., Vaska, L. 1988

机译：通过均相催化合成和N，N-二甲基甲酰胺的氢化还原二氧化碳

Synthesis and reactivity of five-membered palladalactones from arylallenes and carbon dioxide: Relevance to catalytic lactone synthesis

摘要

著录项

相似文献

相关主题

期刊订阅