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首页> 外文期刊>Synthetic Metals >Power factor enhancement via simultaneous improvement of electrical conductivity and Seebeck coefficient in tellurium nanowires/reduced graphene oxide flexible thermoelectric films
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Power factor enhancement via simultaneous improvement of electrical conductivity and Seebeck coefficient in tellurium nanowires/reduced graphene oxide flexible thermoelectric films

机译:通过同时提高碲纳米线/还原氧化石墨烯柔性热电薄膜的电导率和塞贝克系数来提高功率因数

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摘要

The simultaneous improvement of electrical conductivity (sigma) and Seebeck coefficient (S) is essential to realize the thermoelectric materials with high power factor value. Here, we report the discovery that the redox reaction happened between the reduced graphene oxide (RGO) sheets and tellurium (Te) nanowires can lead to a simultaneous improvement of sigma and S in the RGO/Te nanowires hybrid films. With optimization, the electrical conductivity and Seebeck coefficient can reach 633 S/m and 382 mu V/K, respectively, pushing the power factor value up to 68.4 mu W/(mK(2)), approximately 25 times larger than the reported pure Te nanowires film. Based on all of the characterizations, the redox reaction between the RGO sheets and Te nanowires have been confirmed and the transportation characteristics of the hybrid films are predicted. We demonstrate the new approach that via turning the redox reaction, the interfacial interaction can be optimized, enabling a novel flexible thermoelectric films with superior performance. To our knowledge, this is the first time that the TE properties of RGO/inorganic hybrid films are reported. (C) 2015 Elsevier B.V. All rights reserved.
机译:同时实现电导率(sigma)和塞贝克系数(S)的提高对于实现具有高功率因数值的热电材料至关重要。在这里,我们报告的发现,还原的氧化石墨烯(RGO)板和碲(Te)纳米线之间发生的氧化还原反应可以同时改善RGO / Te纳米线混合膜中的sigma和S。通过优化,电导率和塞贝克系数分别可以达到633 S / m和382 mu V / K,从而将功率因数值提高到68.4μW /(mK(2)),约为报告纯净功率的25倍。 Te纳米线薄膜。基于所有的特征,已经证实了RGO片和Te纳米线之间的氧化还原反应,并预测了杂化膜的传输特性。我们演示了通过改变氧化还原反应,可以优化界面相互作用的新方法,从而使新型柔性热电薄膜具有优异的性能。据我们所知,这是首次报道RGO /无机杂化膜的TE特性。 (C)2015 Elsevier B.V.保留所有权利。

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