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首页> 外文期刊>Physica, B. Condensed Matter >Effect of Eu3+ contents on the structure and properties of BaLa_2ZnO_5:Eu~(3+) phosphors
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Effect of Eu3+ contents on the structure and properties of BaLa_2ZnO_5:Eu~(3+) phosphors

机译:Eu3 +含量对BaLa_2ZnO_5:Eu〜(3+)荧光粉结构和性能的影响

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摘要

A series of Eu~(3+) doped BaLa_2ZnO_5 was prepared by a Pechini-type solgel method. The effect of Eu~(3+) concentration on the structure and the luminescent properties of the samples BaLa_(2-x)Eu_xZnO_5 were investigated by powder X-ray diffraction (XRD) and photoluminescence (PL) spectra. The sample adopts the tetragonal or orthorhombic structure as the Eu~(3+) concentration reaches below 1.2 or over 1.6, respectively. The sample is a mixture of tetragonal and orthorhombic phases as the contents of dopants lie between 1.2 and 1.6. The phosphor offers the strongest red light as content of Eu ~(3+) is 0.4. In addition, the crystallization processes of the complex precursors were examined by simultaneous thermogravimetry and differential thermal analysis (TGDTA), and also the optimal heating temperature was investigated.
机译:采用Pechini型溶胶凝胶法制备了一系列Eu〜(3+)掺杂的BaLa_2ZnO_5。通过粉末X射线衍射(XRD)和光致发光(PL)光谱研究了Eu〜(3+)浓度对BaLa_(2-x)Eu_xZnO_5样品结构和发光性能的影响。当Eu〜(3+)浓度分别达到1.2以下或1.6以上时,样品采用四方或正交结构。样品是四方相和正交相的混合物,因为掺杂剂的含量在1.2至1.6之间。当Eu〜(3+)的含量为0.4时,磷光体提供最强的红光。此外,通过同时热重分析和差热分析(​​TGDTA)检查了复杂前体的结晶过程,并研究了最佳加热温度。

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