Rotationally resolved B-X electronic spectra of both conformers of the 1-propoxy radical

Sandhya Gopalakrishnan; Christopher C.Carter; Lily Zu; Vadim Stakhursky; Gyorgy Tarczay; Terry A.Miller

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Rotationally resolved B-X electronic spectra of both conformers of the 1-propoxy radical

机译：1-丙氧基自由基的两个构象物的旋转分辨B-X电子光谱

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Five bands of the B-X laser induced fluorescence spectrum of jet-cooled 1-propoxy radical have been recorded with a spectral resolution of approx = 200 MHz. The resolved rotational and fine structure of these bands has been assigned and analyzed providing rotational constants for both the X and B states as well as components of the electron spin-rotation tensor in the X state. By comparison of these constants with ones obtained from quantum chemistry calculations, two bands have been assigned to the gauche (G) conformer of 1-propoxy and 3 bands to the trans (T) conformer. The spectrum of each conformer abruptly terminates after the excitation of a single C-O stretch.

机译：用B-X激光诱导的喷射冷却的1-丙氧基自由基的荧光光谱的五个带已记录，光谱分辨率约为200 MHz。已分配和分析了这些带的解析旋转和精细结构，并提供了X和B状态的旋转常数以及X状态下电子自旋旋转张量的分量。通过将这些常数与从量子化学计算中获得的常数进行比较，已将两个谱带分配给1-丙氧基的gauche（G）构象异构体，将3个谱带分配给反式（T）构象异构体。每个构象体的光谱在激发单个C-O片段后突然终止。

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《The Journal of Chemical Physics》 |2003年第11期|共16页
作者
Sandhya Gopalakrishnan; Christopher C.Carter; Lily Zu; Vadim Stakhursky; Gyorgy Tarczay; Terry A.Miller;
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1. Rotationally resolved B-X electronic spectra of both conformers of the 1-propoxy radical [J] . Sandhya Gopalakrishnan, Christopher C.Carter, Lily Zu, The Journal of Chemical Physics . 2003,第11期

机译：1-丙氧基自由基的两个构象物的旋转分辨B-X电子光谱
2. Rotationally resolved (B)over-tilde-(X)over-tilde electronic spectra of both conformers of the 1-propoxy radical [J] . Gopalakrishnan S., Carter CC., Zu L., The Journal of Chemical Physics . 2003,第11期

机译：1-丙氧基自由基的两个构象异构体的旋转解析（B）叠峰-（X）叠峰电子光谱
3. Rotationally Resolved Electronic Spectra of the B-X Transition in Multiple Conformers of 1-Butoxy and 1-Pentoxy Radicals [J] . Sandhya Gopalakrishnan, Lily Zu, Terry A. Miller The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2003,第26期

机译：1-丁氧基和1-戊氧基自由基的多个构象异构体中B-X跃迁的旋转分辨电子光谱
4. Spectrally resolved measurements of absorption of broadband UV light-emitting diodes by combustion radicals [C] . Logan W. White, Mirko Gamba AIAA Aerospace Sciences Meeting;AIAA SciTech Forum . 2017

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5. Vibronic structure and rotational spectra of radicals in degenerate electronic state. Case of hydroxymethyl radical and asymmetrically deuterated isotopomers (methoxy isotopomers). [D] . Stakhursky, Vadim Leonidovich. 2005

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6. A Hybrid Program for Fitting Rotationally Resolved Spectra of Floppy Molecules with One Large-Amplitude Rotatory Motion and One Large-Amplitude Oscillatory Motion [O] . Isabelle Kleiner, Jon T. Hougen -1

机译：具有一个大振幅旋转运动和一个大振幅振动运动的软盘分子的旋转分辨谱拟合的混合程序。
7. Rotationally resolved electronic spectra of the ˜B − ˜X transition in multiple conformers of 1-butoxy and 1-pentoxy radicals [O] . Hya Gopalakrishnan, Lily Zu, Terry A. Miller 2003

机译：旋转分辨的1-丁氧基和1-戊氧基的多个构象中~B - ~X跃迁的电子光谱
8. Laser-Induced Fluorescence Studies. The B-X Transition of Cl2. Part 1. Rotationally-Resolved Excitation Spectra and Predissociation in the Excited B 3Pi(0 (+) sub u) State. [R] . Clyne, M. A. A., McDermid, I. S. 1978

机译：激光诱导荧光研究。 Cl2的B-X转换。第1部分：激发B 3pi（0（+）sub u）状态下的旋转分辨激发光谱和预解离。

Rotationally resolved B-X electronic spectra of both conformers of the 1-propoxy radical

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