B-N bond formation at stanna-closo-dodecaborate

Wütz T.; Fleischhauer S.; Wesemann L.

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >B-N bond formation at stanna-closo-dodecaborate

【24h】

B-N bond formation at stanna-closo-dodecaborate

机译：锡烷-氯十二烷中的B-N键形成

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The heteroborate stanna-closo-dodecaborate shows double substitution in the reaction with alkylated acetonitrile. The reaction product, the charge compensated E,E-isomer, was isomerized into the Z,Z-isomer and hydrogenated at the double bonds. Furthermore the methylated cluster shows less reactivity and the monosubstituted cluster was isolated. The reaction products were characterized by elemental analysis and NMR spectroscopy. Three of the substitution products were also characterized by single crystal structure analysis.

机译：在与烷基化乙腈的反应中，杂硼酸酯-异十二烷基-十二烷酸酯显示出双重取代。反应产物，电荷补偿的E，E-异构体，被异构化成Z，Z-异构体并在双键处氢化。此外，甲基化的簇显示出较低的反应性，并且分离了单取代的簇。反应产物通过元素分析和NMR光谱表征。还通过单晶结构分析表征了三种取代产物。

著录项

来源
《Dalton transactions: An international journal of inorganic chemistry》 |2013年第3期|共6页
作者
Wütz T.; Fleischhauer S.; Wesemann L.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词

相似文献

外文文献
中文文献
专利

1. B-N bond formation at stanna-closo-dodecaborate [J] . Wütz T., Fleischhauer S., Wesemann L. Dalton transactions: An international journal of inorganic chemistry . 2013,第3期

机译：锡烷-氯十二烷中的B-N键形成
2. B-N, B-O, and B-CN Bond Formation via Palladium-Catalyzed Cross-Coupling of B-Bromo-Carboranes [J] . Rafal M. Dziedzic, Liban M. A. Saleh, Jonathan C. Axtell, Journal of the American Chemical Society . 2016,第29期

机译：通过钯催化的B-溴代碳硼烷的交叉偶联形成B-N，B-O和B-CN键
3. Alkali metal catalyzed dehydro-coupling of boranes and amines leading to the formation of a B-N bond [J] . Harinath A., Anga Srinivas, Panda Tarun K. RSC Advances . 2016,第42期

机译：碱金属催化硼烷和胺的脱氢偶联，导致B-N键的形成
4. Towards Copper-Copper Direct Bonding: Controlled Crystal Growth of Copper Deposits for Minimization of Interface Formation During Bonding [C] . Ralf Schmidt, Christian Schwarz, Uwe Kirbach, IEEE Electronic Components and Technology Conference . 2021

机译：朝向铜铜直接键合：用于最小化粘接期间界面形成的铜沉积的晶体生长
5. Effects of Local Environment on C?H Bond Scission and Formation and C?O Bond Hydrogenolysis on Late Transition Metal Catalysts [D] . Nie, Haoyu. 2021

机译：局部环境对晚期过渡金属催化剂的C？H粘结和形成和C？O键氢解
6. A unique quinolineboronic acid-based supramolecular structure that relies on double intermolecular B-N bonds for self-assembly in solid state and in solution [O] . Yanling Zhang, Minyong Li, Sekar Chandrasekaran, -1

机译：独特的基于喹啉硼酸的超分子结构依赖于双分子B-N键在固态和溶液中自组装
7. New insights into factors influencing B-N bonding in X:BH 3-nFn and X:BH3-nCln for X=N 2, HCN, LiCN, H2CNH, NF3, NH3 and n=0-3: The importance of deformation [O] . Alkorta Ibon, Elguero José, Del Bene Janet E., 2013

机译：对于X = N 2，HCN，LiCN，H2CNH，NF3，NH3和n = 0-3的X：BH 3-nFn和X：BH3-nCln中B-N键的影响因素的新见解：变形的重要性

B-N bond formation at stanna-closo-dodecaborate

摘要

著录项

相似文献

相关主题

期刊订阅