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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Two high-connected metal-organic frameworks based on d~(10)-metal clusters: Syntheses, structural topologies and luminescent properties
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Two high-connected metal-organic frameworks based on d~(10)-metal clusters: Syntheses, structural topologies and luminescent properties

机译:基于d〜(10)-金属簇的两个高连接金属有机骨架:合成,结构拓扑和发光特性

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摘要

The d~(10)-metal-oxo clusters connected by the asymmetric tricarboxylate and linear neutral ligands give rise to two novel high-connected MOFs. They feature the highest (3,16)- and (3,8)-connected three-dimensional frameworks based on cube-like octanuclear [Zn_8(μ_2-OH) _4(CO_2)_(12)] clusters and butterfly-like tetranuclear [Cd_4(μ_3-OH)_2(CO _2)_6] clusters as the secondary building units, respectively.
机译:由不对称三羧酸盐和线性中性配体连接的d〜(10)-金属-氧代簇产生了两个新颖的高连接MOF。它们具有基于立方状八核[Zn_8(μ_2-OH)_4(CO_2)_(12)]簇和蝶状四核的最高(3,16)-和(3,8)连接的三维框架。 [Cd_4(μ_3-OH)_2(CO _2)_6]分别作为辅助建筑单元。

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