Synthesis of functionalised BTPhen derivatives - effects on solubility and americium extraction

Higginson Matthew A.; Kyle Nichola D.; Marsden Olivia J.; Thompson Paul; Livens Francis R.; Heath Sarah L.

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Synthesis of functionalised BTPhen derivatives - effects on solubility and americium extraction

机译：官能化BTPhen衍生物的合成-对溶解度和a萃取的影响

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Separation of the minor actinides (Am/Cm) from spent nuclear fuel post-PUREX process is expected to play a key part in new reprocessing methodologies. To date, a number of selective americium extractants from the BTPhen ligand family have been identified. In this investigation, we synthesise 24 novel BTPhens with additional functionality to determine the effects on solubilities and americium extraction capabilities. The data obtained will allow for tuning of steric/electronic properties of BTPhens in order to assist future extractant design.

机译：从PUREX后的乏核燃料中分离微量act系元素（Am / Cm）有望在新的后处理方法中发挥关键作用。迄今为止，已经鉴定出许多来自BTPhen配体家族的选择性a提取剂。在这项调查中，我们合成了24种具有附加功能的新型BTPhen，以确定对溶解度和a提取能力的影响。获得的数据将允许调整BTPhen的空间/电子性质，以协助将来的萃取剂设计。

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《Dalton transactions: An international journal of inorganic chemistry》 |2015年第37期|共6页
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Higginson Matthew A.; Kyle Nichola D.; Marsden Olivia J.; Thompson Paul; Livens Francis R.; Heath Sarah L.;
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1. Synthesis of functionalised BTPhen derivatives - effects on solubility and americium extraction [J] . Higginson Matthew A., Kyle Nichola D., Marsden Olivia J., Dalton transactions: An international journal of inorganic chemistry . 2015,第37期

机译：官能化BTPhen衍生物的合成-对溶解度和a萃取的影响
2. Selective Extraction of Americium from Curium and the Lanthanides by the Lipophilic Ligand CyMe(4)BTPhen Dissolved in Aliquat-336 Nitrate Ionic Liquid [J] . Solvent Extraction and Ion Exchange . 2020,第1a4期

机译：通过脂肪酸配体Cyme（4）BTHEN溶解在Aliquat-336硝酸根离子液体中的含含锡和镧系元素的含义的选择性提取
3. Separation of the Minor Actinides Americium(III) and Curium(III) by Hydrophobic and Hydrophilic BTPhen ligands: Exploiting Differences in their Rates of Extraction and Effective Separations at Equilibrium [J] . Lewis Frank W., Harwood Laurence M., Hudson Michael J., Solvent Extraction and Ion Exchange . 2018,第1a4期

机译：通过疏水和亲水性BTPHEN配体分离次要的散光型（III）和含＆℃（III）：利用差异差异，在平衡下的萃取率和有效分离
4. From BTBPs to BTPhens: the effect of ligand pre-organization on the extraction properties of quadridentate bis-triazine ligands [C] . Frank W. Lewis, Laurence M. Harwood, Michael J. Hudson, International conference on nuclear chemistry for sustainable fuel cycles . 2012

机译：从BTBP到BTPHENS：配体预先组织对四柴油双三嗪配体提取性能的影响
5. Synthesis of a water soluble resveratrol derivative as a potential anti-cancer drug. [D] . Essel, Augustine Foster. 2010

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6. Tandem sequential catalytic enantioselective synthesis of highly-functionalised tetrahydroindolizine derivatives [O] . Shuyue Zhang, Mark D. Greenhalgh, Alexandra M. Z. Slawin, 2020

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7. Direct Selective Extraction of Trivalent Americium from PUREX Raffinate Using a Combination of CyMe4BTPhen and TEDGA—A Feasibility Study [O] . Lange, Steve, Wilden, Andreas, Modolo, Giuseppe, 2018

机译：CyMe4BTPhen和TEDGA的组合直接从P药残液中直接萃取三价meric的可行性研究
8. Synthesis of crystalline americium hydroxide, Am(OH)(sub 3), and determination of its enthalpy of formation; estimation of the solubility-product constants of actinide(III) hydroxides. [R] . Morss, L. R., Williams, C. W. 1993

机译：合成结晶氢氧化铟，am（OH）（sub 3），并确定其形成焓;估计肌动蛋白（III）氢氧化物的溶解度 - 产物常数。

Synthesis of functionalised BTPhen derivatives - effects on solubility and americium extraction

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