An unusual highly emissive water-soluble iridium lissamine-alanine complex and its use in a molecular logic gate

Oliveira Elisabete; Santos Sergio M.; Nunez Cristina; Capelo Jose Luis; Lodeiro Carlos

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An unusual highly emissive water-soluble iridium lissamine-alanine complex and its use in a molecular logic gate

机译：一种不寻常的高发射水溶性铱赖氨酸-丙氨酸络合物及其在分子逻辑门中的应用

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The interaction of iridium(III) with a new lissamine rhodamine B sulfonyl derivative, bearing alanine as a building block, (1) with an orange emission in water results in a green highly emissive Ir@1 complex at room temperature. The new Ir@1 complex can sense the toxic Hg2+ metal ion and cysteine. Based on such properties, a new sophisticated molecular logic gate with three inputs was designed.

机译：铱（III）与一种新的赖氨酸罗丹明B磺酰基衍生物（以丙氨酸为结构单元）之间的相互作用（1）在水中呈橙色发射，在室温下会生成绿色的高发射Ir @ 1配合物。新的Ir @ 1络合物可以感知有毒的Hg2 +金属离子和半胱氨酸。基于这些特性，设计了具有三个输入的新型复杂分子逻辑门。

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《Dalton transactions: An international journal of inorganic chemistry》 |2016年第3期|共5页
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Oliveira Elisabete; Santos Sergio M.; Nunez Cristina; Capelo Jose Luis; Lodeiro Carlos;
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1. An unusual highly emissive water-soluble iridium lissamine-alanine complex and its use in a molecular logic gate [J] . Oliveira Elisabete, Santos Sergio M., Nunez Cristina, Dalton transactions: An international journal of inorganic chemistry . 2016,第3期

机译：一种不寻常的高发射水溶性铱赖氨酸-丙氨酸络合物及其在分子逻辑门中的应用
2. Guanidinate ligated iridium(III) complexes with various cyclometaiated ligands: synthesis, structure, and highly efficient electrophosphorescent properties with a wide range of emission colours [J] . Virendra Kumar Rai, Masayoshi Nishiura, Masanori Takimoto Journal of Materials Chemistry, C. materials for optical and electronic devices . 2013,第4期

机译：胍盐与多种环甲基化配体连接的铱（III）配合物：合成，结构和高效的电致磷光性质，具有多种发射颜色
3. Highly Selective Cysteine Detection and Bioimaging in Zebrafish through Emission Color Change of Water-Soluble Conjugated Polymer-Based Assay Complex [J] . Na Young Kwon, Daigeun Kim, Geunseok Jang ACS applied materials & interfaces . 2012,第3期

机译：水溶性共轭聚合物基检测复合物的发射颜色变化在斑马鱼中的高选择性半胱氨酸检测和生物成像
4. Water-soluble iridium phosphorescent complexes for OLED applications [C] . Min-Sik Eum, Heekoo Yoon, Tae Hyung Kim . 2012

机译：OLED应用的水溶性铱磷光配合物
5. Theoretical studies on intermolecular versus intramolecular carbon-hydrogen bond activation in rhodium, iridium, and zirconium complexes, and on the ethene to hydridovinyl interconversion in rhodium and iridium complexes [D] . Jimenez-Catano, Rogelio. 1995

机译：铑，铱和锆络合物中分子间和分子内碳氢键活化的理论研究，以及铑和铱络合物中乙烯向氢化乙烯基的相互转化的理论研究
6. Aggregation-Enhanced Emission of Gold NanoclustersInduced by Serum Albumin and Its Application to Protein Detectionand Fabrication of Molecular Logic Gates [O] . Zhenzhen Huang, Min Wang, Zilong Guo, 2018

机译：金纳米团簇的聚集增强发射血清白蛋白诱导的蛋白及其在蛋白质检测中的应用逻辑门的设计与制造
7. Unusual dual-emissive heteroleptic iridium complexes incorporating TADF cyclometalating ligands [O] . Helen Benjamin, Yonghao Zheng, Valery N. Kozhevnikov, 2020

机译：不寻常的双发射异素铱络合物，其掺入TADF环荷载配体

An unusual highly emissive water-soluble iridium lissamine-alanine complex and its use in a molecular logic gate

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