Reactions of a persistent phosphinyl radical/diphosphine with heteroallenes

Giffin Nick A.; Hendsbee Arthur D.; Masuda Jason D.

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Reactions of a persistent phosphinyl radical/diphosphine with heteroallenes

机译：持久性次膦酰基基团/二膦与杂戊烯的反应

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The persistent phosphinyl radical, (H2C)(2)(NDipp)(2)P center dot, formed upon dissolution from the homolytic cleavage of the P-P bond in the diphosphane [(H2C)(2)(NDipp)(2)P](2), was reacted with carbon disulfide, phenyl isocyanate, and phenyl isothiocyanate. The phosphinyl fragments add across the C=S or C=O double bond to give neutral, diamagnetic species.

机译：持久性次膦基自由基（H2C）（2）（NDipp）（2）P中心点是由二膦中的PP键的均裂裂解而溶解而形成的[（H2C）（2）（NDipp）（2）P] （2）与二硫化碳，异氰酸苯酯和异硫氰酸苯酯反应。次膦酰基片段通过C = S或C = O双键加成，形成中性的反磁性物质。

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《Dalton transactions: An international journal of inorganic chemistry》 |2016年第32期|共3页
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Giffin Nick A.; Hendsbee Arthur D.; Masuda Jason D.;
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1. Reactions of a persistent phosphinyl radical/diphosphine with heteroallenes [J] . Giffin Nick A., Hendsbee Arthur D., Masuda Jason D. Dalton transactions: An international journal of inorganic chemistry . 2016,第32期

机译：持久性次膦酰基基团/二膦与杂戊烯的反应
2. Correction to Preparation of a Diphosphine with Persistent Phosphinyl Radical Character in Solution: Characterization, Reactivity with O2, S8, Se, Te, and P4, and Electronic Structure Calculations [J] . Nick A. Giffin, Arthur D. Hendsbee, Tracey L. Roemmele, Inorganic Chemistry . 2013,第1期

机译：溶液中具有持久性膦酰基自由基特征的二膦的制备的校正：表征，与O2，S8，Se，Te和P4的反应性以及电子结构计算
3. Preparation of a diphosphine with persistent phosphinyl radical character in solution: Characterization, reactivity with O _2, S _8, Se, Te, and P _4, and electronic structure calculations [J] . Giffin N.A., Hendsbee A.D., Roemmele T.L., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2012,第21期

机译：溶液中具有持久性次膦酰基自由基特征的二膦的制备：表征，与O _2，S _8，Se，Te和P _4的反应性以及电子结构计算
4. Generation of α-Iminyl Radicals from α-Bromo N-Sulfonylimines by Photoredox Catalyst and Application to Various Radical Reactions [C] . Naoto Esumi, Kensuke Suzuki, Yoshihiro Nishimoto 日本化学会春季年会講演予稿集 . 2018

机译：通过光致毒剂催化剂从α-溴N-磺酰胺产生α-亚二烯基的产生，并应用于各种自由基反应
5. Strategic detoxification of aqueous -phase persistent organic pollutants using enzyme-mediated radical reactions. [D] . Colosi, Lisa M. 2007

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6. Addition and Cycloaddition Reactions of Phosphinyl- and Phosphonyl-2H-Azirines Nitrosoalkenes and Azoalkenes [O] . Américo Lemos 2009

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7. Persistent Phosphinyl Radicals Featuring a Bulky Amino Substituent and the 2, 6-Bis(trifluoromethyl)phenyl Group [O] . -1

机译：具有庞大的氨基取代基和2,6-双（三氟甲基）苯基的持久性膦基自由基
8. Reactions of Dianionic Carbonylmetalates with Heteroallenes: Reduction of Carbonylsulfide, Thioisocyanates, Isocyanates and Carbodiimides by Group 6 and 8 Carbonylmetalates [R] . Lee, G. R., Cooper, N. J. 1988

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Reactions of a persistent phosphinyl radical/diphosphine with heteroallenes

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