A novel off-on fluorescent chemosensor for Al3+ derived from a 4,5-diazafluorene Schiff base derivative

Li Hui; Wang Jianzhi; Zhang ShuJiang; Gong ChenLiang; Wang Feng

首页> 外文期刊>RSC Advances >A novel off-on fluorescent chemosensor for Al3+ derived from a 4,5-diazafluorene Schiff base derivative

【24h】

A novel off-on fluorescent chemosensor for Al3+ derived from a 4,5-diazafluorene Schiff base derivative

机译：用于Al3 +的新型荧光化学传感器，衍生自4,5-二氮氟胞胞席克夫基衍生物

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The performance of a chemosensor is closely related to its structure. A new Schiff bass (DFSB) based on 4,5-diazafluorene units has been synthesized in this work. The interaction of DFSB with different metal ions has been studied using UV-vis absorption spectra and fluorescent spectra. The results show that DFSB is a highly selective and sensitive probe for Al3+ ions over other commonly coexisting metal ions in ethanol. A very obvious fluorescence enhancement effect was observed, and a turn-on ratio over 1312-fold was triggered with the addition of 10 equiv. of Al3+ ions. What is more, such fluorescent responses could be detected by the naked eye under a UV-lamp. The lowest detection limit for Al3+ was determined as 3.7 x 10(-8) M. The complex solution (DFSB-Al3+) exhibited reversibility with EDTA. These results may be caused by the unique molecular structure.

机译：化学传感器的性能与其结构密切相关。基于4,5-diazafluorene单元的新Schiff低音（DFSB）已在这项工作中合成。使用UV-Vis吸收光谱和荧光光谱研究了DFSB与不同金属离子的相互作用。结果表明，DFSB是Al3 +离子的高度选择性和敏感的探针，其在乙醇中的其他通常共存的金属离子上。观察到一个非常明显的荧光增强效果，并在增加10当量时触发1312倍的接通比率。 Al3 +离子。更重要的是，可以通过UV灯下的肉眼检测这种荧光反应。 Al3 +的最低检测限定为3.7×10（-8）M.复合溶液（DFSB-AL3 +）与EDTA表现出可逆性。这些结果可能是由独特的分子结构引起的。

著录项

来源
《RSC Advances》 |2018年第56期|共6页
作者
Li Hui; Wang Jianzhi; Zhang ShuJiang; Gong ChenLiang; Wang Feng;
展开▼
作者单位

Wuhan Inst Technol Sch Chem Engn &

Pharm Minist Educ Key Lab Green Chem Proc Wuhan 430205 Hubei Peoples R China;

Wuhan Inst Technol Sch Chem Engn &

Pharm Minist Educ Key Lab Green Chem Proc Wuhan 430205 Hubei Peoples R China;

Lanzhou Univ Coll Chem &

Chem Engn Lanzhou 730000 Gansu Peoples R China;

Lanzhou Univ Coll Chem &

Chem Engn Lanzhou 730000 Gansu Peoples R China;

Wuhan Inst Technol Sch Chem Engn &

Pharm Minist Educ Key Lab Green Chem Proc Wuhan 430205 Hubei Peoples R China;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词

相似文献

外文文献
中文文献
专利

1. A novel off-on fluorescent chemosensor for Al3+ derived from a 4,5-diazafluorene Schiff base derivative [J] . Li Hui, Wang Jianzhi, Zhang ShuJiang, RSC Advances . 2018,第56期

机译：用于Al3 +的新型荧光化学传感器，衍生自4,5-二氮氟胞胞席克夫基衍生物
2. Novel 4,5-diazafluorene-based Schiff base derivatives as Al3+ ions fluorescence turn-on sensors [J] . Zhang Shu Jiang, Li Hui, Gong Chen Liang, Synthetic Metals . 2016,第Null期

机译：新型基于4,5-二氮杂芴的Schiff碱衍生物作为Al3 +离子的荧光开启传感器
3. Water-soluble fluorescent chemosensor based on Schiff base derivative terminated PEG for highly efficient detection of Al3+ in pure aqueous media [J] . Xu Yuhang, Li Leixuan, Bai Liping, Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2020,第40期

机译：基于Schiff碱衍生物终止PEG的水溶性荧光化学传感器，用于纯含水介质中的AL3 +高效检测
4. TWO HIGHLY SENSITIVE AND SELECTIVE COLORIMETRIC "OFF-ON" RHODAMINE-BASED FLUORESCENT CHEMOSENSOR FOR DIVALENT MERCURIC ION DETECTION [C] . yong Ye, man li, Di Zhang, International astronautical congress . 2013

机译：两种高度灵敏和选择性的“关”式基于罗丹明的荧光化学传感器用于不同的汞离子检测
5. Probing the Adsorption Behavior of 4,5-Diazafluoren-9-one and Its Schiff Base Derivatives on SIlver and Gold Nanosurfaces Using Raman Spectroscopy, Density Functional Theory and Potential Energy Distribution Calculations. [D] . McCoy, Rhonda Patrice. 2012

机译：使用拉曼光谱，密度泛函理论和势能分布计算，探讨4，5-二氮杂芴-9-一及其席夫碱衍生物在银和金纳米表面上的吸附行为。
6. Highly Sensitive and Selective Colorimetric and Off-On Fluorescent Reversible Chemosensors for Al3+ Based on the Rhodamine Fluorophore [O] . Naveen Mergu, Ashok Kumar Singh, Vinod Kumar Gupta 2015

机译：基于若丹明荧光团的Al3 +的高灵敏度和选择性比色和可开式荧光可逆化学传感器
7. Highly Sensitive and Selective Colorimetric and Off-On Fluorescent Reversible Chemosensors for Al3+ Based on the Rhodamine Fluorophore [O] . Naveen Mergu, Ashok Kumar Singh, Vinod Kumar Gupta 2015

机译：基于罗丹明荧光团的al3 +高灵敏度和选择性比色和开启式荧光可逆化学传感器

A novel off-on fluorescent chemosensor for Al3+ derived from a 4,5-diazafluorene Schiff base derivative

摘要

著录项

相似文献

相关主题

期刊订阅