Solvent-free and room temperature microwave-assisted direct C7 allylation of indolines via sequential C-H and C-C activation

Wang Qiuling; Shi Linlin; Liu Shuang; Zhi Changlei; Fu Lian-Rong; Zhu Xinju; Hao Xin-Qi; Song Mao-Ping

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Solvent-free and room temperature microwave-assisted direct C7 allylation of indolines via sequential C-H and C-C activation

机译：无溶剂和室温微波辅助Incoline通过顺序C-H和C-C活化进行吲哚吲哚的直接C7烯丙基化

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A Ru or Rh-catalyzed efficient and atom-economic C7 allylation of indolines with vinylcyclopropanes was developed via sequential C-H and C-C activation. A wide range of substrates were well tolerated to afford the corresponding allylated indolines in high yields and E/Z selectivities under microwave irradiation. The obtained allylated indolines could further undergo transformations to afford various value-added chemicals. Importantly, this reaction proceeded at room temperature under solvent-free conditions.

机译：通过顺序C-H和C-C活化显着与乙烯基环丙烷的吲哚或Rh催化的高效和原子经济C7烯丙基化。耐受宽范围的基材，得到在微波辐射下高产率和E / Z选择性的相应烯丙基吲哚吲哚。所得烯丙基吲哚吲哚可能进一步经历转化以提供各种增值化学品。重要的是，在无溶剂条件下，该反应在室温下进行。

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《RSC Advances》 |2020年第18期|共5页
作者
Wang Qiuling; Shi Linlin; Liu Shuang; Zhi Changlei; Fu Lian-Rong; Zhu Xinju; Hao Xin-Qi; Song Mao-Ping;
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Zhengzhou Univ Coll Chem 100 Sci Rd Zhengzhou 450001 Henan Peoples R China;

Zhengzhou Univ Coll Chem 100 Sci Rd Zhengzhou 450001 Henan Peoples R China;

Zhengzhou Univ Coll Chem 100 Sci Rd Zhengzhou 450001 Henan Peoples R China;

Zhengzhou Univ Coll Chem 100 Sci Rd Zhengzhou 450001 Henan Peoples R China;

Zhengzhou Univ Coll Chem 100 Sci Rd Zhengzhou 450001 Henan Peoples R China;

Zhengzhou Univ Coll Chem 100 Sci Rd Zhengzhou 450001 Henan Peoples R China;

Zhengzhou Univ Coll Chem 100 Sci Rd Zhengzhou 450001 Henan Peoples R China;

Zhengzhou Univ Coll Chem 100 Sci Rd Zhengzhou 450001 Henan Peoples R China;

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正文语种 eng
中图分类化学;
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1. Solvent-free and room temperature microwave-assisted direct C7 allylation of indolines via sequential C-H and C-C activation [J] . Wang Qiuling, Shi Linlin, Liu Shuang, RSC Advances . 2020,第18期

机译：无溶剂和室温微波辅助Incoline通过顺序C-H和C-C活化进行吲哚吲哚的直接C7烯丙基化
2. Solvent-free and room temperature microwave-assisted direct C7 allylation of indolines via sequential C–H and C–C activation [J] . Qiuling Wang, Linlin Shi, Shuang Liu, RSC Advances . 2020,第18期

机译：无溶剂和室温微波辅助Incoline通过顺序C-H和C-C活化进行吲哚吲哚的直接C7烯丙基化
3. Rhodium(III)-Catalyzed Direct C7 Allylation of Indolines via Sequential C-H and C-C Activation [J] . Wang Qiuling, Zhi Chang-Lei, Lu Pei-Pei, Advanced synthesis & catalysis . 2019,第6期

机译：铑（III）通过顺序C-H和C-C活化 - 催化吲哚的直接C7烯丙基化
4. Efficient synthesis of highly funetionalized Indoles and Indolines by C-H bond activation [C] . T. Droge, J. J. Neumann, S. Rakshit European Symposium on Organic Chemistry . 2009

机译：通过C-H键活化有效地合成高浊度吲哚和吲哚吲哚
5. C-H bond activation and C-C bond formation at adjacent metals. [D] . Torkelson, Jeffrey Robert. 1998

机译：在相邻金属处的C-H键活化和C-C键形成。
6. Rhodium-Catalyzed C-C Bond Formation via Heteroatom-Directed C-H Bond Activation [O] . Denise A. Colby, Robert G. Bergman, Jonathan A. Ellman -1

机译：经由杂原子的定向C-H键活化铑催化的C-C键的形成
7. Rhodium-Catalyzed C-C Bond Formation via Heteroatom-Directed C-H Bond Activation [O] . Colby, Denise, Bergman, Robert, Ellman, Jonathan 2010

机译：通过杂原子导向的C-H键活化形成铑催化的C-C键

Solvent-free and room temperature microwave-assisted direct C7 allylation of indolines via sequential C-H and C-C activation

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