Ruthenium-Catalyzed Hydrogenation of Carbocyclic Aromatic Amines: Access to Chiral Exocyclic Amines

Yan Zhong; Xie Huan-Ping; Shen Hong-Qiang; Zhou Yong-Gui

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Ruthenium-Catalyzed Hydrogenation of Carbocyclic Aromatic Amines: Access to Chiral Exocyclic Amines

机译：钌催化碳环芳族胺的氢化：进入手性官方胺

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摘要

The first highly enantioselective hydrogenation of carbocyclic aromatic amines has been successfully realized using in situ-generated chiral ruthenium complex as catalyst, affording facile access to chiral exocyclic amines with up to 98% ee.

机译：碳环芳族胺的首批高度映选择性氢化已经使用原位产生的手性钌络合物作为催化剂成功实现，这是对含有高达98％ee的手性官方胺的容易获得。

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《Organic letters》 |2018年第4期|共4页
作者
Yan Zhong; Xie Huan-Ping; Shen Hong-Qiang; Zhou Yong-Gui;
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Chinese Acad Sci Dalian Inst Chem Phys State Key Lab Catalysis Dalian 116023 Peoples R China;

Chinese Acad Sci Dalian Inst Chem Phys State Key Lab Catalysis Dalian 116023 Peoples R China;

Chinese Acad Sci Dalian Inst Chem Phys State Key Lab Catalysis Dalian 116023 Peoples R China;

Chinese Acad Sci Dalian Inst Chem Phys State Key Lab Catalysis Dalian 116023 Peoples R China;

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正文语种 eng
中图分类有机化学;
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专利

1. Ruthenium-Catalyzed Hydrogenation of Carbocyclic Aromatic Amines: Access to Chiral Exocyclic Amines [J] . Yan Zhong, Xie Huan-Ping, Shen Hong-Qiang, Organic letters . 2018,第4期

机译：钌催化碳环芳族胺的氢化：进入手性官方胺
2. Ruthenium-catalyzed transfer hydrogenation of aromatic ketones with aminophosphine or bis(phosphino)amine ligands derived from isopropyl substituted anilines [J] . Aydemir M, Baysal A Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2010,第4期

机译：钌催化的氨基酮或衍生自异丙基取代苯胺的双（膦）胺配体的芳族酮转移加氢
3. Synthesis of chiral primary amines: diastereoselective alkylation of N-[(1E)-alkylidene]-3,5-bis[(1S)-1-methoxyethyl]-4H-1,2,4-triazol-4-amines and N-4-N-exocyclic bond cleavage in the resulting 1,2,4-triazol-4-alkylamines [J] . Serradeil-Albalat M, Roussel C, Vanthuyne N, Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2008,第23期

机译：手性伯胺的合成：N-[（1E）-亚烷基] -3,5-双[（1S）-1-甲氧基乙基] -4H-1,2,4-三唑-4-胺和N-的非对映选择性烷基化生成的1,2,4-三唑-4-烷基胺中的4-N-环外键裂解
4. Chiral amines by asymmetric hydrogenation processes [C] . Andre H.M. de Vries, Gerard K.M. Verzijl, Laurent Lefort Process Development Symposium . 2013

机译：通过不对称氢化过程的手性胺
5. Transition metal-catalyzed asymmetric hydrogenation for synthesis of chiral amines. [D] . Chang, Mingxin. 2013

机译：过渡金属催化的不对称氢化用于手性胺的合成。
6. Towards a general ruthenium-catalyzed hydrogenation of secondary and tertiary amides to amines [O] . Jose R. Cabrero-Antonino, Elisabetta Alberico, Kathrin Junge, 2018

机译：迈向一般钌催化的仲酰胺和叔酰胺氢化为胺
7. Towards a general ruthenium-catalyzed hydrogenation of secondary and tertiary amides to amines [O] . Jose R. Cabrero-Antonino, Elisabetta Alberico, Kathrin Junge, 2016

机译：朝向一般的钌催化氢化氢化氢和叔酰胺至胺

Ruthenium-Catalyzed Hydrogenation of Carbocyclic Aromatic Amines: Access to Chiral Exocyclic Amines

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