A mechanochromic cyclemetalated cationic Ir(III) complex with AIE activity by strategic modification of ligands

Pei Yu; Xie Jiaxin; Cui Dongxu; Liu Shengnan; Li Guangfu; Zhu Dongxia; Su Zhongmin

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >A mechanochromic cyclemetalated cationic Ir(III) complex with AIE activity by strategic modification of ligands

【24h】

A mechanochromic cyclemetalated cationic Ir(III) complex with AIE activity by strategic modification of ligands

机译：通过配体的战略性改性，机械光学型环丙烯酸阳离子IR（III）复合物与AIE活动

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Two new aggregation-induced emission (AIE)-active cyclemetalated cationic Ir(m) complexes have been rationally designed and synthesized by introducing O-H substituents into Schiff base ligands. pi-Hydrogen bonding is successfully exploited for the first time to realize the mechanochromic luminescence (MCL) property by the synergistic effect of O-H and F substituents in complex 1. An X-ray crystal structure analysis of the two complexes suggests that the intramolecular hydrogen bonding effectively restricted the molecular motions, thus causing typical AIE characteristics. More importantly, a loosely packed structure constructed from intermolecular hydrogen bonding interactions (O-H center dot center dot center dot pi and C-H center dot center dot center dot F) is obtained, and it is susceptible to mechanical stimulation. Powder X-ray diffraction (PXRD) studies also prove that the MCL behavior of complex 1 is caused by the reversible phase transition from crystalline to amorphous state under grinding and solvent recrystallization, leading to a change in emission colors. A re-writable phosphorescence data recording device was fabricated using complex 1 as the active material. Our molecular design strategies provide a new avenue for achieving efficient phosphorescence materials with AIE and MCL properties.

机译：通过将O-H取代基引入Schiff碱配体，两种新的聚集诱导的发射（AIE） - 活性衔接性阳离子IR（M）配合物已经合理设计和合成。首次成功利用PI-氢键来实现通过复合物1中的OH和F取代基的协同作用来实现机械变色发光（MCL）性能。两种复合物的X射线晶体结构分析表明分子内氢键有效地限制了分子运动，从而引起典型的AIE特征。更重要的是，获得由分子间氢键相互作用（O-H中心点中心点中心点PI和C-H中心点中心点FOT F）构成的松散填充结构，并且易于机械刺激。粉末X射线衍射（PXRD）研究还证明了复合物1的MCL行为是由在研磨和溶剂重结晶下从结晶与无定形状态的可逆相转变引起的，导致发射颜色的变化。使用复合物1作为活性材料制造可重用的磷光数据记录装置。我们的分子设计策略为实现了AIE和MCL性质的高效磷光材料提供了新的途径。

著录项

来源
《Dalton transactions: An international journal of inorganic chemistry》 |2020年第37期|共6页
作者
Pei Yu; Xie Jiaxin; Cui Dongxu; Liu Shengnan; Li Guangfu; Zhu Dongxia; Su Zhongmin;
展开▼
作者单位

Northeast Normal Univ Key Lab Nanobiosensing &

Nanobioanal Univ Jilin P Dept Chem 5268 Renmin St Changchun 130024 Jilin Peoples R China;

Northeast Normal Univ Key Lab Nanobiosensing &

Nanobioanal Univ Jilin P Dept Chem 5268 Renmin St Changchun 130024 Jilin Peoples R China;

Northeast Normal Univ Key Lab Nanobiosensing &

Nanobioanal Univ Jilin P Dept Chem 5268 Renmin St Changchun 130024 Jilin Peoples R China;

Northeast Normal Univ Key Lab Nanobiosensing &

Nanobioanal Univ Jilin P Dept Chem 5268 Renmin St Changchun 130024 Jilin Peoples R China;

Northeast Normal Univ Key Lab Nanobiosensing &

Nanobioanal Univ Jilin P Dept Chem 5268 Renmin St Changchun 130024 Jilin Peoples R China;

Northeast Normal Univ Key Lab Nanobiosensing &

Nanobioanal Univ Jilin P Dept Chem 5268 Renmin St Changchun 130024 Jilin Peoples R China;

Northeast Normal Univ Key Lab Nanobiosensing &

Nanobioanal Univ Jilin P Dept Chem 5268 Renmin St Changchun 130024 Jilin Peoples R China;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;无机化学;
关键词

相似文献

外文文献
中文文献
专利

1. A mechanochromic cyclemetalated cationic Ir(III) complex with AIE activity by strategic modification of ligands [J] . Pei Yu, Xie Jiaxin, Cui Dongxu, Dalton transactions: An international journal of inorganic chemistry . 2020,第37期

机译：通过配体的战略性改性，机械光学型环丙烯酸阳离子IR（III）复合物与AIE活动
2. Cationic dinuclear Ir(III) complexes based on acylhydrazine ligands: Reversible piezochromic luminescence and AIE behaviours [J] . Dyes and Pigments . 2020,第期

机译：基于酰肼配体的阳离子二核IR（III）配合物：可逆压力色调发光和AIE行为
3. Multifunctional Cationic Iridium(III) Complexes Bearing 2-Aryloxazolo[4,5-f][1,10]phenanthroline ((NN)-N-Lambda) Ligand: Synthesis, Crystal Structure, Photophysics, Mechanochromic/Vapochromic Effects, and Reverse Saturable Absorption [J] . Zhu Xiaolin, Cui Peng, Kilina Svetlana, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2017,第22期

机译：多功能阳离子铱（III）复合物轴承2-芳基恶唑[4,5-F] [1,10]菲啉（（NN）-N-Lambda）配体：合成，晶体结构，光学药物，机械粒细胞/ vopoMochic效应，以及相反的饱和度吸收
4. Cationic Uranium Alkyl Complexes of a Rigid NON-Donor Pincer Ligand: The Impact of Arene-Coordination on Ethylene Polymerization Activity [C] . David J. H. Emslie, N. R. Andreychuk, B. Vidjayacoumar Rare Earth Research Conference . 2019

机译：刚性非供体钳配体的阳离子铀烷基复合物：芳烃配位对乙烯聚合活性的影响
5. MANGANESE(II) AND COBALT(III) COMPLEXES OF MULTIDENTATE LIGANDS: I. MANGANESE(II) COMPLEXES OF A MACROCYCLIC PENTADENTATE LIGAND. II. COBALT(III) COMPLEXES OF LINEAR TETRAMINE LIGANDS. [D] . HAMILTON, HOBART GORDON, JR. 1968

机译：多齿配体的锰（II）和钴（III）配合物：I.大环戊二烯配体的锰（II）配合物。二。线性叔丁胺配体的钴（III）配合物。
6. Synthesis Properties and Light-Emitting ElectrochemicalCell (LEEC) Device Fabrication of Cationic Ir(III) Complexes BearingElectron-Withdrawing Groups on the Cyclometallating Ligands [O] . Amlan K. Pal, David B. Cordes, Alexandra M. Z. Slawin, -1

机译：合成性质和发光电化学带有阳离子的Ir（III）配合物的电池（LEEC）装置制造环金属化配体上的吸电子基团
7. Strategic modification of ligands for remarkable piezochromic luminescence (PCL) based on a neutral Ir(iii) phosphor [O] . Dan Li, Guangfu Li, Jiaxin Xie, 2019

机译：基于中性IR（III）磷光体的显着压力色调发光（PCL）的配体的战略改性

A mechanochromic cyclemetalated cationic Ir(III) complex with AIE activity by strategic modification of ligands

摘要

著录项

相似文献

相关主题

期刊订阅