Mixed er-NHC/phosphine Pd(ii) complexes and their catalytic activity in the Buchwald-Hartwig reaction under solvent-free conditions

Ageshina Alexandra A.; Sterligov Grigorii K.; Rzhevskiy Sergey A.; Topchiy Maxim A.; Chesnokov Gleb A.; Gribanov Pavel S.; Melnikova Elizaveta K.; Nechaev Mikhail S.; Asachenko Andrey F.; Bermeshev Maxim V.

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Mixed er-NHC/phosphine Pd(ii) complexes and their catalytic activity in the Buchwald-Hartwig reaction under solvent-free conditions

【24h】

Mixed er-NHC/phosphine Pd(ii) complexes and their catalytic activity in the Buchwald-Hartwig reaction under solvent-free conditions

机译：在无溶剂条件下，混合ER-NHC /磷酸Pd（II）复合物及其在Buchwald-Hartwig反应中的催化活性

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A series of novel (NHC) PdCl2-PR3 complexes were synthesized and fully characterized by H-1, C-13, P-31 NMR and FT-IR spectroscopy. These complexes showed high catalytic activity toward solvent-free Buchwald-Hartwig amination. Both primary and secondary amines were efficiently utilized under the same reaction conditions. The solvent-free synthesis of valuable N-aryl carbazoles and similar N-heterocyclic systems was described.

机译：通过H-1，C-13，P-31 NMR和FT-IR光谱合成了一系列新颖（NHC）PdCl2-PR3配合物并完全表征。这些配合物向无溶剂Buchwald-Hartwig胺化显示出高催化活性。在相同的反应条件下有效地使用初级和仲胺。描述了无溶剂合成有价值的N-芳基咔唑和类似的N-杂环体系。

著录项

来源
《Dalton transactions: An international journal of inorganic chemistry》 |2019年第10期|共6页
作者
Ageshina Alexandra A.; Sterligov Grigorii K.; Rzhevskiy Sergey A.; Topchiy Maxim A.; Chesnokov Gleb A.; Gribanov Pavel S.; Melnikova Elizaveta K.; Nechaev Mikhail S.; Asachenko Andrey F.; Bermeshev Maxim V.;
展开▼
作者单位

Russian Acad Sci AV Topchiev Inst Petrochem Synth Leninsky Prospect 29 Moscow 119991 Russia;

Russian Acad Sci AV Topchiev Inst Petrochem Synth Leninsky Prospect 29 Moscow 119991 Russia;

Russian Acad Sci AV Topchiev Inst Petrochem Synth Leninsky Prospect 29 Moscow 119991 Russia;

Russian Acad Sci AV Topchiev Inst Petrochem Synth Leninsky Prospect 29 Moscow 119991 Russia;

Russian Acad Sci AV Topchiev Inst Petrochem Synth Leninsky Prospect 29 Moscow 119991 Russia;

Russian Acad Sci AV Topchiev Inst Petrochem Synth Leninsky Prospect 29 Moscow 119991 Russia;

Moscow MV Lomonosov State Univ Leninskie Gory 1 3 Moscow 119991 Russia;

Russian Acad Sci AV Topchiev Inst Petrochem Synth Leninsky Prospect 29 Moscow 119991 Russia;

Russian Acad Sci AV Topchiev Inst Petrochem Synth Leninsky Prospect 29 Moscow 119991 Russia;

Russian Acad Sci AV Topchiev Inst Petrochem Synth Leninsky Prospect 29 Moscow 119991 Russia;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;无机化学;
关键词

相似文献

外文文献
中文文献
专利

1. Mixed er-NHC/phosphine Pd(ii) complexes and their catalytic activity in the Buchwald-Hartwig reaction under solvent-free conditions [J] . Ageshina Alexandra A., Sterligov Grigorii K., Rzhevskiy Sergey A., Dalton transactions: An international journal of inorganic chemistry . 2019,第10期

机译：在无溶剂条件下，混合ER-NHC /磷酸Pd（II）复合物及其在Buchwald-Hartwig反应中的催化活性
2. Synthesis, Structures of Benzoxazolyl Iridium(III) Complexes, and Applications on C-C and C-N Bond Formation Reactions under Solvent-Free Conditions: Catalytic Activity Enhanced by Noncoordinating Anion without Silver Effect [J] . Dawei Wang, Keyan Zhao, Chongying Xu ACS catalysis . 2014,第11期

机译：无溶剂条件下苯并恶唑基铱（III）配合物的合成，结构及其在C-C和C-N键形成反应中的应用：非银的非配位阴离子增强了催化活性
3. Pd(II) complexes with mixed benzothiazolin-2-ylidene and phosphine ligands and their catalyic activities toward C-C coupling reactions [J] . Yen SK, Koh LL, Huynh HV, Dalton transactions: An international journal of inorganic chemistry . 2008,第5期

机译：具有混合的苯并噻唑啉-2-亚烷基和膦配体的Pd（II）配合物及其对C-C偶联反应的催化活性
4. Reactions of Secondary Phosphine with Various Mononuclear Platinum(II) Complexes [C] . Masaki Kakeya, Kohtaro Osakada Symposium on Organometallic Chemistry . 2007

机译：二次膦与各种单核铂（II）复合物的反应
5. I. New remote radical chain functionalization reactions. II. Structure and reactivity of polycyclic nitrogen heterocycle-chlorine radical complexes. III. Studies towards catalytic radical relay chlorination reactions. [D] . Wiedenfeld, David John. 1993

机译：I.新的远程自由基链功能化反应。二。多环氮杂环-氯自由基配合物的结构和反应性。三，对催化自由基中继氯化反应的研究。
6. NHC Pd(II) and Ag(I) Complexes: Synthesis Structureand Catalytic Activity in Three Types of C–C Coupling Reactions [O] . Qing-Xiang Liu, *, Ze-Liang Hu, 2018

机译：NHC Pd（II）和Ag（I）配合物：合成结构和三种类型的CC偶联反应的催化活性
7. Nickel(II) complexes with bifunctional phosphine–imidazolium ligands and their catalytic activity in the Kumada–Corriu coupling reaction [O] . Joffrey Wolf, Agnès Labande, Jean-Claude Daran, 2006

机译：镍（II）配合物，具有双官能膦 - 咪唑鎓配体及其在Kumada-Corriu偶联反应中的催化活性
8. Dialkylamino Phosphorus Metal Carbonyls. 2. Bis(diisopropylamino)phosphido and (Diisopropylamino)phosphinidene Metal Carbonyl Complexes from Reactions of Manganese and Cobalt Carbonyls with Bis(diisopropylamino)phosphine [R] . King, R. B., Fu, W. K., Holt, E. M. 1986

机译：二烷基氨基磷酸金属羰基化合物。 2.来自锰和羰基钴与双（二异丙基氨基）膦的反应的双（二异丙基氨基）膦基和（二异丙基氨基）亚膦基金属羰基配合物

Mixed er-NHC/phosphine Pd(ii) complexes and their catalytic activity in the Buchwald-Hartwig reaction under solvent-free conditions

摘要

著录项

相似文献

相关主题

期刊订阅