Chiral two bladed ML2 metallamacrocycles: design, structures and solution behavior

Soudry Hannah; Desmarets Christophe; Gontard Geoffrey; Edgington Tiffany; Cooksy Andrew L.; Amouri Hani

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Chiral two bladed ML2 metallamacrocycles: design, structures and solution behavior

机译：手性两种Bladed ML2金属缩缩衣：设计，结构和解决方案行为

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Chiral two bladed complexes of [Co(L)(2)][BF4](2) (1) and [Zn(L)(2)][BF4](2) (2) containing an atropoisomeric semi-rigid bidentate ligand L were synthesized and characterized. They are obtained as homochiral species but in a racemic mixture via a ligand self-sorting mechanism. These enantiomers can be differentiated in solution using optically active anions.

机译：[Co（1）（2）] [BF4] [BF4] [BF4]（2）（1）和[Zn（L）（2）] [BF4]（2）（2）的手性两种叶片复合物含有阿托异构半刚性二齿配体 L合成并表征。它们作为初型物种获得，但通过配体自分粉机构以外消旋混合物。这些对映体可以使用光学活性阴离子在溶液中进行分化。

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《Dalton transactions: An international journal of inorganic chemistry》 |2017年第31期|共6页
作者
Soudry Hannah; Desmarets Christophe; Gontard Geoffrey; Edgington Tiffany; Cooksy Andrew L.; Amouri Hani;
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Univ Paris 06 UPMC Univ Paris 06 Sorbonne Univ IPCM UMR 8232 4 Pl Jussieu F-75252 Paris 05 France;

Univ Paris 06 UPMC Univ Paris 06 Sorbonne Univ IPCM UMR 8232 4 Pl Jussieu F-75252 Paris 05 France;

Univ Paris 06 UPMC Univ Paris 06 Sorbonne Univ IPCM UMR 8232 4 Pl Jussieu F-75252 Paris 05 France;

San Diego State Univ Dept Chem San Diego CA 92182 USA;

San Diego State Univ Dept Chem San Diego CA 92182 USA;

Univ Paris 06 UPMC Univ Paris 06 Sorbonne Univ IPCM UMR 8232 4 Pl Jussieu F-75252 Paris 05 France;

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正文语种 eng
中图分类化学;无机化学;
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1. Chiral two bladed ML2 metallamacrocycles: design, structures and solution behavior [J] . Soudry Hannah, Desmarets Christophe, Gontard Geoffrey, Dalton transactions: An international journal of inorganic chemistry . 2017,第31期

机译：手性两种Bladed ML2金属缩缩衣：设计，结构和解决方案行为
2. Chiral C-2 and C-1 symmetric (cyclooctane-1,5-diyl)bis(2-pyrazolyl)borate complexes of potassium and thallium. Preparation, structures and solution behavior [J] . Chisholm MH., Streib WE., Iyer SS. New Journal of Chemistry . 2000,第6期

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3. Highly Eu3+ ions doped novel red emission solid solution phosphors Ca18Li3(Bi,Eu)(PO4)(14): structure design, characteristic luminescence and abnormal thermal quenching behavior investigation [J] . Zhu Ge, Li Zhuowei, Wang Chuang, Dalton transactions: An international journal of inorganic chemistry . 2019,第5期

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4. Effect of the Different Structure of the Chiral Core on Phase Behaviors of Cholesteric Star-Shaped Liquid Crystals [C] . Mei Tian, Xiao-Zhi He, Dan-Shu Yao, International Conference on Advanced Engineering Materials and Technology . 2011

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5. Phase transitions, crystallization behaviors and structure of a nonracemic chiral main-chain liquid crystalline polyester and its macroscopic quasi-monodomains. [D] . Jin, Shi. 2001

机译：非外消旋手性主链液晶聚酯及其宏观准单畴的相变，结晶行为和结构。
6. Design and Synthesis of Chiral Zn2+ Complexes Mimicking Natural Aldolases for Catalytic C–C Bond Forming Reactions in Aqueous Solution [O] . Susumu Itoh, Shotaro Sonoike, Masanori Kitamura, 2014

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7. Poly(p-phenylene)-type polymer composed of an (R,R)-C2-symmetric chiral recurring unit: Solution behavior, packing structure, and large circular dichroism observed with a film of the polymer [O] . Takakazu Yamamoto, Takayuki Iijima, Yoshiki Ozawa, 2006

机译：聚（对亚苯基） - 型聚合物由（R，R）-C2 - 对称手性手性重复单元：用聚合物薄膜观察到的溶液行为，包装结构和大的圆形二色性
8. A Rapid Blade-to-Blade Solution for Use in Turbomachinery Design [R] . Mcfarland, E. R. 1982

机译：用于涡轮机械设计的快速刀片到刀片解决方案

Chiral two bladed ML2 metallamacrocycles: design, structures and solution behavior

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