Chain, sheet and framework structures in the adducts of phenylphosphonic acid with 4,4 '-bipyridyl (1/1), piperazine (2/1) and 1,4-diazabicyclo[2.2.2]octane (2/1)

Ferguson G.; Gregson RM.; Meehan PR.; Glidewell C.

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Chain, sheet and framework structures in the adducts of phenylphosphonic acid with 4,4 '-bipyridyl (1/1), piperazine (2/1) and 1,4-diazabicyclo[2.2.2]octane (2/1)

机译：苯基膦酸与4,4'-联吡啶（1/1），哌嗪（2/1）和1,4-二氮杂双环[2.2.2]辛烷（2/1）的加合物中的链，片和骨架结构

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Phenylphosphonic acid-4,4'-bipyridyl (1/1), (1), C6H7O3P C10H8N2, triclinic, P (1) over bar, a = 6.9026(8), b= 9.7086(9), c = 12.201(2)Angstrom, alpha = 77.138(9), beta= 74.345(10), gamma = 75.477(8)degrees with Z = 2, is a salt, C10H9N2+[C6H5PO2(OH)](-), containing singly protonated 4,4'-bipyridyl cations: the cations and anions are linked by N-H ... O and C-H ... O hydrogen bonds in an R-2(2)(7) motif and these aggregates are linked into centrosymmetric R-2(2)(8) dimers by O-H ... O hydrogen bonds; the dimer units are linked into chains by CH ... O hydrogen bonds. Phenylphosphonic acid-piperazine (2/1), (C6H7O3P)(2) . C4H10N2 (2), monoclinic, P2(1), a = 6.0042(9), b = 19.746(3), c = 8.651 (2) Angstrom, beta = 105.63(2)degrees with Z = 2, is a salt, C4H12N22+ - [{C6H5PO2(OH)}(-)](2), containing doubly protonated piperazine: the anions are linked by O-H ... O hydrogen bonds into centrosymmetric R-2(2)(8) dimers and these dimers are linked to the centrosymmetric cations by N-H ... O hydrogen bonds: each cation is hydrogen-bonded to four different anion dimers and each anion dimer is hydrogen-bonded to four different cations; the overall structure consists of two-dimensional sheets built from R-6(4)(16) and R-4(4)(18) rings. Phenylphosphonic acid-1,4-diazabicyclo [2.2.2] octane (2/1), (3), (C6H7O3P)(2) . C6H12N2, monoclinic, P2(1), a= 6.3607(3), b = 21.8300(11), c = 14.5965(9)Angstrom, beta = 92.558 (6)degrees, with Z = 4, is a salt in which one nitrogen of the diamine is fully protonated and the other is partially protonated: the anionic components are linked into C(4) chains by O-H ... O hydrogen bonds, and these chains are cross-linked via the diamines by means of N-H ... O and O-H ... N hydrogen bonds. The resulting sheets built from R-8(8)(34) rings are linked by C-H ... O hydrogen bonds into a three-dimensional framework. [References: 34]

机译：苯基膦酸4,4'-联吡啶（1/1），（1），C6H7O3P C10H8N2，三斜晶系，P（1）大于bar，a = 6.9026（8），b = 9.7086（9），c = 12.201（2埃，α= 77.138（9），beta = 74.345（10），γ= 75.477（8）度，Z = 2，是一种盐C10H9N2 + [C6H5PO2（OH）]（-），包含质子化的4,4 '-联吡啶基阳离子：阳离子和阴离子通过R-2（2）（7）主题中的NH ... O和CH ... O氢键连接，并且这些聚集体连接成中心对称的R-2（2）（8）通过OH…O氢键形成的二聚体;二聚体单元通过CH ... O氢键连接成链。苯基膦酸哌嗪（2/1），（C6H7O3P）（2）。 C4H10N2（2），单斜晶系，P2（1）/ n，a = 6.0042（9），b = 19.746（3），c = 8.651（2）埃，β= 105.63（2）度，Z = 2，是盐，C4H12N22 +-[{C6H5PO2（OH）}（-）]（2），含有双质子化的哌嗪：阴离子通过OH ... O氢键连接成中心对称的R-2（2）（8）二聚体，这些二聚体通过NH ... O氢键与中心对称阳离子相连：每个阳离子与四个不同的阴离子二聚体氢键合，每个阴离子二聚体与四个不同的阳离子氢键合。整体结构由R-6（4）（16）和R-4（4）（18）环组成的二维薄板组成。苯基膦酸-1,4-二氮杂双环[2.2.2]辛烷（2/1），（3），（C6H7O3P）（2）。 C6H12N2，单斜晶系，P2（1）/ n，a = 6.3607（3），b = 21.8300（11），c = 14.5965（9）埃，β= 92.558（6）度，Z = 4，是一种盐二胺中的一个氮被完全质子化，另一个被部分质子化：阴离子成分通过OH ... O氢键连接到C（4）链中，这些链通过NH经由二胺交联O和OH N氢键由R-8（8）（34）环构建的所得薄片通过C-H ... O氢键连接成三维框架。 [参考：34]

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《Acta Crystallographica, Section B. Structural Science》 |1998年第2期|共10页
作者
Ferguson G.; Gregson RM.; Meehan PR.; Glidewell C.;
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正文语种 eng
中图分类晶体学;
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O hydrogen-bonds; Crystal-structure; Refinement; Patterns;

机译：O氢键;晶体结构;精炼;模式;

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1. Chain, sheet and framework structures in the adducts of phenylphosphonic acid with 4,4 '-bipyridyl (1/1), piperazine (2/1) and 1,4-diazabicyclo[2.2.2]octane (2/1) [J] . Ferguson G., Gregson RM., Meehan PR., Acta Crystallographica, Section B. Structural Science . 1998,第2期

机译：苯基膦酸与4,4'-联吡啶（1/1），哌嗪（2/1）和1,4-二氮杂双环[2.2.2]辛烷（2/1）的加合物中的链，片和骨架结构
2. Formation of one-dimensional chains, two-dimensional bilayers and a three-dimensional diamondoid architecture in hydrogen-bonded adducts of 4,4 '-biphenol with 1,4-diazabicyclo[2.2.2]octane and 1,2-diaminoethane [J] . Ferguson G., Gregson RM., Meehan PR., Acta Crystallographica, Section B. Structural Science . 1998,第2期

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7. Surface-Enhanced Raman Scattering of the Protonated Forms of 1,4-Diazabicyclo(2.2.2)Octane at a Silver Electrode. [R] . Guzonas, D. A., Irish, D. E., Atkinson, G. F. 1989

机译：质子化形式的1,4-二氮杂双环（2.2.2）辛烷在银电极上的表面增强拉曼散射。

Chain, sheet and framework structures in the adducts of phenylphosphonic acid with 4,4 '-bipyridyl (1/1), piperazine (2/1) and 1,4-diazabicyclo[2.2.2]octane (2/1)

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