Oxygen-promoted Suzuki-Miyaura reaction of aryl fluorosulfates and potassium aryltrifluoroborates: Mild and efficient access to biaryls and terphenyls

Li Xinmin; Ma Yunhai; Hu Qinghong; Jiang Bo; Wu Qing; Yuan Zeli

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Oxygen-promoted Suzuki-Miyaura reaction of aryl fluorosulfates and potassium aryltrifluoroborates: Mild and efficient access to biaryls and terphenyls

机译：氧氟磺酸盐和芳基三氟硼酸钾的氧促进的铃木 - 宫系反应：轻度和有效地进入芳基团和三苯基

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摘要

A mild and efficient protocol has been developed for the Suzuki-Miyaura reaction of aryl fluorosulfates and potassium aryltrifluoroborates at room temperature. A series of biaryls can be prepared with excellent yields in this system and an aerobic atmosphere demonstrates a positive effect on the reactivity of the cross-coupling reactions. Additionally, this method can be extended to one-pot double Suzuki-Miyaura reactions, allowing the synthesis of various unsymmetrical terphenyls in moderate to good yields.

机译：已经为芳基氟磺酸盐和芳基三氟硼硼酸钾在室温下进行了温和和高效的方案。可以在该系统中具有优异产量的一系列前列，并且有氧气氛证明了对交叉偶联反应的反应性的积极影响。另外，该方法可以扩展到单盆双铃木 - Miyaura反应，允许在中等至良好的产率中合成各种非对称的三苯基。

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来源
《Catalysis Communications》 |2018年第2018期|共6页
作者
Li Xinmin; Ma Yunhai; Hu Qinghong; Jiang Bo; Wu Qing; Yuan Zeli;
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作者单位

Zunyi Med Univ Sch Pharm Zunyi Peoples R China;

Zunyi Med Univ Sch Pharm Zunyi Peoples R China;

Zunyi Med Univ Sch Pharm Zunyi Peoples R China;

Zunyi Med Univ Sch Pharm Zunyi Peoples R China;

Zunyi Med Univ Sch Pharm Zunyi Peoples R China;

Zunyi Med Univ Sch Pharm Zunyi Peoples R China;

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原文格式 PDF
正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词
Suzuki-Miyaura reaction; Aryl fluorosulfate; Potassium aryltrifluoroborate; One-pot; Terphenyls;

机译：Suzuki-miyaura反应;芳基氟磺酸盐;芳基氟硼酸钾;一锅;三苯基;

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专利

1. Oxygen-promoted Suzuki-Miyaura reaction of aryl fluorosulfates and potassium aryltrifluoroborates: Mild and efficient access to biaryls and terphenyls [J] . Li Xinmin, Ma Yunhai, Hu Qinghong, Catalysis Communications . 2018,第期

机译：氧氟磺酸盐和芳基三氟硼酸钾的氧促进的铃木 - 宫系反应：轻度和有效地进入芳基团和三苯基
2. Oxygen-promoted Pd/C-catalyzed Suzuki-Miyaura reaction of potassium aryltrifluoroborates [J] . Chun Liu, Chao Liu, Xin-Min Li, 中国化学快报（英文版） . 2016,第005期

机译：氧促进的Pd / C催化的芳基三氟硼酸钾的Suzuki-Miyaura反应
3. Oxygen-Promoted Suzuki-Miyaura Reaction for Efficient Construction of Biaryls [J] . Liu Chun, Li Xinmin Chemical record . 2016,第1期

机译：氧气促进的Suzuki-Miyaura反应有效构建联芳基
4. Suzuki-Miyaura Reaction Using Biphenylene-containing Ruthenocenylphosphine (R-Phos): Synthesis of Tetra-ortho-substituted Biaryl from Aryl Chloride [C] . Takashi Hoshi, Ippei Saitoh, Toshio Suzuki Symposium on Organometallic Chemistry . 2007

机译：铃木宫果酰胺反应使用含有联苯的钌烯基（R-PHOS）的反应：从芳氯的芳基的四右替代的芳丙齐芳基
5. Functionalized organotrifluoroborates: Synthesis and reactivity. I.Suzuki-Miyaura reactions of aryl- and heteroaryl trifluoroborates with aryl- and heteroaryl triflates. II. Oxidation of hydroxyl-containing trifluoroborates. III. Suzuki-Miyaura reactions of potassium trifluoroboratohomoenolates. IV. Development of a HRMS method for organotrifluoroborates [D] . Petrillo, Daniel E. 2008

机译：功能化的有机三氟硼酸酯：合成与反应性。芳基-和杂芳基三氟硼酸酯与芳基-和杂芳基三氟甲磺酸酯的I.Suzuki-Miyaura反应。二。含羟基的三氟硼酸盐的氧化。三，三氟硼硼酸同戊烯酸钾的Suzuki-Miyaura反应。 IV。研发有机三氟硼酸盐的HRMS方法
6. Suzuki-Miyaura Cross-Coupling Reactions of Benzyl Halides with Potassium Aryltrifluoroborates [O] . Gary A. Molander, Maxwell D. Elia -1

机译：卤化苄与芳基三氟硼酸钾的Suzuki-Miyaura交叉偶联反应
7. Suzuki-Miyaura Cross-Coupling Reactions of Aryl Tellurides with Potassium Aryltrifluoroborate Salts [O] . -1

机译：Suzuki-miyaura芳基碲化酸亚芳基芳基氟硼酸钾的交叉偶联反应

Oxygen-promoted Suzuki-Miyaura reaction of aryl fluorosulfates and potassium aryltrifluoroborates: Mild and efficient access to biaryls and terphenyls

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