Interfacial Synthetic Approach for Constructing Metal-Organic Framework Crystals Using Metal Ion-Doped Polymer Substrate

Tsuruoka Takaaki; Kumano Misato; Mantani Koji; Matsuyama Tetsuhiro; Miyanaga Ayumi; Ohhashi Takashi; Takashima Yohei; Minami Hideto; Suzuki Toyoko; Imagawa Kaori; Akamatsu Kensuke

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Interfacial Synthetic Approach for Constructing Metal-Organic Framework Crystals Using Metal Ion-Doped Polymer Substrate

机译：金属离子掺杂的聚合物基体界面合成金属有机骨架晶体的方法

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We report a new paradigm for the synthesis of metal organic framework (MOP) crystals with controlled thickness by utilizing interfacial self-assembly of frameworks on metal ion-doped polymer precursors. The approach involves preparation of metal ion-doped polymer precursors through ion-exchange reactions and synthesis of MOF crystals by immersion into solutions containing organic ligands. The thickness of the resulting MOF crystals can be readily controlled by the number of doped-metal ions in the polymer precursors. MOF crystals could be very important and potentially useful for applications, and the present approach based on interfacial self-assembly could significantly advance MOF crystal preparation techniques.

机译：我们报告了一种新的范式，用于通过利用金属离子掺杂的聚合物前驱体上的骨架的界面自组装来合成具有受控厚度的金属有机骨架（MOP）晶体。该方法涉及通过离子交换反应制备金属离子掺杂的聚合物前体，以及通过浸入含有机配体的溶液中合成MOF晶体。可以通过聚合物前体中的掺杂金属离子的数量来容易地控制所得MOF晶体的厚度。 MOF晶体可能非常重要，并可能对应用程序有用，并且基于界面自组装的本方法可以显着提高MOF晶体的制备技术。

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《Crystal growth & design》 |2016年第5期|共5页
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Tsuruoka Takaaki; Kumano Misato; Mantani Koji; Matsuyama Tetsuhiro; Miyanaga Ayumi; Ohhashi Takashi; Takashima Yohei; Minami Hideto; Suzuki Toyoko; Imagawa Kaori; Akamatsu Kensuke;
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正文语种 eng
中图分类晶体学;
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1. Interfacial Synthetic Approach for Constructing Metal-Organic Framework Crystals Using Metal Ion-Doped Polymer Substrate [J] . Tsuruoka Takaaki, Kumano Misato, Mantani Koji, Crystal growth & design . 2016,第5期

机译：金属离子掺杂的聚合物基体界面合成金属有机骨架晶体的方法
2. Controlling the Orientation of Metal–Organic Framework Crystals by an Interfacial Growth Approach Using a Metal Ion-Doped Polymer Substrate [J] . Takashi Ohhashi, Takaaki Tsuruoka, Seiya Fujimoto, Crystal growth & design . 2018,第1期

机译：使用金属离子掺杂聚合物基材通过界面生长方法控制金属 - 有机框架晶体的取向
3. Morphology Control of Metal-Organic Frameworks Based on Paddle-Wheel Units on Ion-Doped Polymer Substrate Using an Interfacial Growth Approach [J] . Tsuruoka Takaaki, Mantani Koji, Miyanaga Ayumi, Langmuir: The ACS Journal of Surfaces and Colloids . 2016,第24期

机译：界面生长法在离子掺杂聚合物基底上基于桨轮单元的金属有机骨架的形貌控制
4. Wrapping Flexible Metal-Organic Frameworks with Organic Polymers via Site-Specific Radical Polymerization from Its Crystal Surface [C] . Yohei Takashima, Kenji Fukudome, Takaaki Tsuruoka 日本化学会春季年会講演予稿集 . 2018

机译：将柔性金属 - 有机框架与其晶体表面的特异性自由基聚合包裹着有机聚合物
5. Synthesis and Post-Synthetic Transmetalations of Metal-Organic Frameworks Containing Bimetallic Centers. [D] . Veleta, Jose Miguel. 2017

机译：包含双金属中心的金属有机骨架的合成和合成后的重金属化。
6. Three Novel Lanthanide Metal-Organic Frameworks (Ln-MOFs) Constructed by Unsymmetrical Aromatic Dicarboxylatic Tectonics: Synthesis Crystal Structures and Luminescent Properties [O] . Ya-Pan Wu, Dong-Sheng Li, Wei Xia, 2014

机译：非对称芳族二羧酸构造构造的三种新型镧系金属有机骨架（Ln-MOFs）：合成晶体结构和发光性质
7. X-ray crystallographic insights into post-synthetic metalation products in a metal-organic framework [O] . Huxley, M., Coghlan, C., Bloch, W., 2017

机译：X射线晶体学洞察到金属 - 有机骨架中的合成后金属化产物

Interfacial Synthetic Approach for Constructing Metal-Organic Framework Crystals Using Metal Ion-Doped Polymer Substrate

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