Two novel metal-organic frameworks (MOFs) with (3,6)-connected net topologies: Syntheses, crystal structures, third-order nonlinear optical and luminescent properties

Zou J.-P.; Peng Q.; Wen Z.; Zeng G.-S.; Xing Q.-J.; Guo G.-C.

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Two novel metal-organic frameworks (MOFs) with (3,6)-connected net topologies: Syntheses, crystal structures, third-order nonlinear optical and luminescent properties

机译：具有（3,6）连接的净拓扑结构的两个新颖的金属有机框架（MOF）：合成，晶体结构，三阶非线性光学和发光特性

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Two novel metal-organic frameworks (MOFs) [Cu_3(C _7H_2NO_5)_2]_n· 3nH_2O (1) and [CuAg_2(C_7H_3NO _5)_2]_n (2) were obtained by the hydrothermal reaction. Complex 1 exhibits a three-dimensional (3,6)-connected anatase topology with the Schlfli symbol (4~2.6)_2(4 ~4.6~2.8~8.10), while complex 2 displays a two-dimensional (3,6)-connected TiS_2 related net topology with the Schlfli symbol (4~3)_2(4~6.6~6.8 ~3). The optical studies show that 1 and 2 both have good third-order nonlinear optical and luminescent properties.

机译：通过水热反应获得了两个新颖的金属有机骨架（MOF）[Cu_3（C _7H_2NO_5）_2] _n·3nH_2O（1）和[CuAg_2（C_7H_3NO_5）_2] _n（2）。配合物1显示具有Schlfli符号（4〜2.6）_2（4〜4.6〜2.8〜8.10）的三维（3,6）连接的锐钛矿拓扑，而配合物2显示二维（3,6）-用Schlfli符号（4〜3）_2（4〜6.6〜6.8〜3）连接TiS_2相关的网络拓扑。光学研究表明1和2都具有良好的三阶非线性光学和发光特性。

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《Crystal growth & design》 |2010年第6期|共7页
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Zou J.-P.; Peng Q.; Wen Z.; Zeng G.-S.; Xing Q.-J.; Guo G.-C.;
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中图分类晶体学;
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1. Two novel metal-organic frameworks (MOFs) with (3,6)-connected net topologies: Syntheses, crystal structures, third-order nonlinear optical and luminescent properties [J] . Zou J.-P., Peng Q., Wen Z., Crystal growth & design . 2010,第6期

机译：具有（3,6）连接的净拓扑结构的两个新颖的金属有机框架（MOF）：合成，晶体结构，三阶非线性光学和发光特性
2. Cobalt(II)-Lanthanide(III) Heterometallic Metal-Organic Frameworks with Unique (6,6)-Connected Nia Topologies with 1H-1,2,3-Triazole-4,5-dicarboxylic Acid: Syntheses, Structures and Magnetic Properties [J] . Ji-Yong Zou, Wei Shi, Na Xu, European journal of inorganic chemistry . 2014,第2期

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3. Two high-connected metal-organic frameworks based on d~(10)-metal clusters: Syntheses, structural topologies and luminescent properties [J] . Song X.-Z., Song S.-Y., Zhao S.-N., Dalton transactions: An international journal of inorganic chemistry . 2013,第23期

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机译：新金属 - 有机单晶的合成，晶体结构，热和非线性光学性能：Tetrabromo（Piperazinium）锌酸锌（II）（TBPZ）
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6. Three Novel Lanthanide Metal-Organic Frameworks (Ln-MOFs) Constructed by Unsymmetrical Aromatic Dicarboxylatic Tectonics: Synthesis Crystal Structures and Luminescent Properties [O] . Ya-Pan Wu, Dong-Sheng Li, Wei Xia, 2014

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Two novel metal-organic frameworks (MOFs) with (3,6)-connected net topologies: Syntheses, crystal structures, third-order nonlinear optical and luminescent properties

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