Synthesis of a novel nonsymmetrical bimacrocyclic ligand comprised of triaza and tetraaza macrocycles and its Dinckel(II)complexes

Katsura Mochizuki; Yasunori Numata

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Synthesis of a novel nonsymmetrical bimacrocyclic ligand comprised of triaza and tetraaza macrocycles and its Dinckel(II)complexes

机译：用三氮和四氮杂癌及其南克尔（II）配合物组成新的非对称双环状配体的新型非对称双环循环配体

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摘要

A novel nonsymmetrical bimacrocyclic ligand,in which triaza(tacn)and teraaza(L)macrocycles are linked by a 2-hydroxy-trimethylene bridge,and two new kinds of dinickel(II)complexes with this ligand have been synthesized and characterized.

机译：一种新的非对称双环循环配体，其中三氮（TACN）和Teraaza（L）宏杂种通过2-羟基三甲基桥连接，并合成了具有该配体的两种新的Dinickel（II）络合物并表征。

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来源
《Inorganic Chemistry Communications》 |2004年第6期|共3页
作者
Katsura Mochizuki; Yasunori Numata;
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作者单位

Division of Chemistry Graduate School of Integrated Science Yokohama City University 22-2 Seto Kanazawa-ku Yokohama 236-0027 Japan;

Division of Chemistry Graduate School of Integrated Science Yokohama City University 22-2 Seto Kanazawa-ku Yokohama 236-0027 Japan;

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原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
synthesis; nonsymmetrical ligand; nickel(II)complex; bimacrocycle;

机译：合成;非对称配体;镍（II）复合物;Bimrocycle;

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专利

1. Synthesis of a novel nonsymmetrical bimacrocyclic ligand comprised of triaza and tetraaza macrocycles and its Dinckel(II)complexes [J] . Katsura Mochizuki, Yasunori Numata Inorganic Chemistry Communications . 2004,第6期

机译：用三氮和四氮杂癌及其南克尔（II）配合物组成新的非对称双环状配体的新型非对称双环循环配体
2. Structural Study of Ga(III), In(III), and Fe(lII) Complexes of Triaza-Macrocycle Based Ligands with N3S3 Donor Set [J] . Johannes Notni, Karolin Pohle, Joop A. Peters, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2009,第7期

机译：基于Triaza-Macrocycle的配体与N3S3供体组的Ga（III），In（III）和Fe（II）配合物的结构研究
3. Kinetics and Mechanism of the Ligand Exchange Reaction Between Tetraaza Macrocycle Ligand and Cu(II) Tetradentate Amine-Amide Complexes [J] . Vafazadeh Rasoul, Zare-Sadrabadi Ghasem Acta Chimica Slovenica . 2015,第4期

机译：Tetraaza大环配体与Cu（II）四齿胺-酰胺配合物之间配体交换反应的动力学和机理
4. Synthesis and Characterization of Mono and Mixed Ligand, Ni(II), Pd(II) and Pt(II) Complexes of S-5-Phenyl -1, 3, 4-Oxadiazole-2-yl Benzothioate with some Tertiary Diphosphines Ligands [C] . R. A. Saleh, H. A. Mohammad, T. I. Gerber, International Conference and Workshops on Basic and Applied Sciences . 2017

机译：S-5-苯基-1,3,4-二氧化氮-2-基苯并噻吩二叔二膦配体的S-5-苯基-1,3,4-二氮唑-2-基苯甲酸酯的单氧和混合配体，Ni（II），Pd（II）和Pt（II）配合物的合成及表征
5. X-RAY CRYSTALLOGRAPHIC STUDIES OF TRANSITION METAL COMPLEXES: I. COORDINATIVELY SELECTIVE MIXED-METAL COMPLEXES; II. COPPER(II) -TETRA-THIAETHER AND -TETRAAZA MACROCYCLES. [D] . GAVEL, DIANE PAULINE -1

机译：过渡金属配合物的X射线晶体学研究：I.协同选择性混合金属配合物；二。铜（II）-四硫杂环丁烷和-四氮杂-甲基。
6. Synthesis of Binucleating Macrocycles and their Nickel(II) Hydroxo- and Cyano-Bridged Complexes with Divalent Ions: Anatomical Variation of Ligand Features [O] . Xiaofeng Zhang, Deguang Huang, Yu-Sheng Chen, -1

机译：Binucleating大环及其镍（II）Hydroxo-和氰基桥联配合物的二价离子的合成：配体解剖变异的特点
7. Halogenation of Mixed Ligand Cobalt(III) Complexes with 12- or 13-Membered Tetraaza Macrocycle and Acetylacetone, CoZaneN4(acac)(ClO4)2(Z=12, 13) [O] . Akira Hirano, Naohide Matsumoto, Akira Ohyoshi 1983

机译：混合配体钴（III）配合物的卤化与12-或13元四氧化物大环和乙酰丙酮，CO Z Anen4（ACAC）（CLO 4）2（Z = 12,13）

Synthesis of a novel nonsymmetrical bimacrocyclic ligand comprised of triaza and tetraaza macrocycles and its Dinckel(II)complexes

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