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Study on corrosion property of a series of hexafluorophosphate ionic liquids on steel surface

机译:一系列六氟磷酸盐离子液体在钢表面的腐蚀性能研究

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Room temperature ionic liquids were found to be a kind of versatile lubricant with excellent friction reduction, antiwear performance. However, our knowledge is insufficient for understanding their corrosive properties. In the present work, the effects of a series of 1-n-alkyl-3-methylimidazolium hexafluorophosphates on the corrosion properties of AISI 52100 carbon steels were studied using potentiodynamic polarisation, electrochemical impedance spectroscopy and electrochemical noise. The results show that the corrosion activity decreases with increasing the chain length of alkyl substituent. The corrosion ability of 1-decyl-3-methylimidazolium hexafluorophosphate was the lowest among four kinds of 1-n-alkyl-3-methylimidazolium hexafluorophosphates absolute alcohol solution.
机译:人们发现室温离子液体是一种通用的润滑剂,具有优异的减摩,抗磨性能。但是,我们的知识不足以了解其腐蚀性。在本工作中,使用电位动力学极化,电化学阻抗谱和电化学噪声研究了一系列1-n-烷基-3-甲基咪唑鎓六氟磷酸盐对AISI 52100碳钢的腐蚀性能的影响。结果表明,腐蚀活性随烷基取代基链长的增加而降低。 1-癸基-3-甲基咪唑六氟磷酸盐的腐蚀能力在四种1-n-烷基-3-甲基咪唑六氟磷酸盐无水溶液中最低。

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