Two New Series of Potentially Triboluminescent Lanthanide(III) β‐Diketonate Complexes

Margenfeld Leif‐Kenneth; Liebing Phil; Oehler Florian; Lorenz Volker; Engelhardt Felix; Hilfert Liane; Busse Sabine; Edelmann Frank T.

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Two New Series of Potentially Triboluminescent Lanthanide(III) β‐Diketonate Complexes

机译：两种新的潜在累卷发镧系元素（III）β-二酮晶络合物

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> Two new series of anionic lanthanide(III) tetrakis(dibenzoylmethanato) complexes of the type [C ₄ H ₈ NEtH][ Ln (dbm) ₄ ] [ Ln = Pr ( 2a ), Nd ( 2b ), Eu ( 2c ), Tb ( 2d ), Lu ( 2e ); dbm = dibenzoylmethanate anion; [C ₄ H ₈ NEtH] + = N ‐ethylpyrrolidinium cation] and [C ₅ H ₁₀ NEtH][ Ln (dbm) ₄ ] [ Ln = Pr ( 3a ), Nd ( 3b ), Eu ( 3c ), Tb ( 3d ), Lu ( 3e ); [C ₅ H ₁₀ NEtH] + = N ‐ethylpiperidinium cation]. The results showed that anions of the type [ Ln (dbm) ₄ ] – are accessible for Ln 3+ ions covering a wide range of ionic radii. While neither 2c nor 3c showed the expected triboluminescence (TL) properties, the new TL‐active europium(III) complex salt [ i Pr ₂ NH ₂ ][Eu(dbm) ₄ ] ( 4 ) could be isolated in a similar manner. Moreover, the unexpected formation and structural characterization of the nonanuclear europium cluster Eu ₉ (μ

机译： >两种新的阴离子镧系元素（III）四（二苯甲酰比）络合物的类型[C _{4 H _{8 neth] [ ln （dBm）_{4 ] [ ln = pr（ 2a ），nd（ 2b ），欧盟（ 2c ），tb（ 2d ），lu（ 2e ）; DBM =二苯甲酰甲烷类阴离子; [C _{4 h _{8 neth] + = n / el> - 乙基吡咯烷阳离子]和[c _{5 < / sub> h _{10 neth] [ ln （dBm）_{4 ] [ ln = pr（ 3a ），Nd（ 3b ），eu（ 3c ），tb（ 3d ），lu（ 3e < / b>）; [C _{5 H _{10 neth] + = n℃ - 乙基哌啶阳离子]。结果表明，[1> Ln （dBm）_{4 ] - 的阴离子可用于 ln ^{3 + / sup>离子覆盖各种离子半径。虽然既不是 2c / b>也不显示出预期的累氮发光（tl）性质，新的TL-活性铕（III）复合物盐[ i pr <亚> 2 NH _{2 ] [欧盟（dBm）_{4 ]（ 4 ）可以以类似的方式分离。此外，非核铕簇EU _{9 （μ
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来源
《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2018年第19期|共8页
作者
Margenfeld Leif‐Kenneth; Liebing Phil; Oehler Florian; Lorenz Volker; Engelhardt Felix; Hilfert Liane; Busse Sabine; Edelmann Frank T.;
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Chemisches InstitutOtto‐von‐Guericke‐Universit?t MagdeburgUniversit?tsplatz 2 39106 Magdeburg Germany;

Laboratorium für Anorganische ChemieETH ZürichVladimir‐Prelog‐Weg 2 8093 Zürich Switzerland;

Institut für Chemie/Anorganische ChemieMartin‐Luther‐Universit?t Halle‐WittenbergKurt‐Mothes‐Str. 2 06120 Halle (Saale) Germany;

Chemisches InstitutOtto‐von‐Guericke‐Universit?t MagdeburgUniversit?tsplatz 2 39106 Magdeburg Germany;

Chemisches InstitutOtto‐von‐Guericke‐Universit?t MagdeburgUniversit?tsplatz 2 39106 Magdeburg Germany;

Chemisches InstitutOtto‐von‐Guericke‐Universit?t MagdeburgUniversit?tsplatz 2 39106 Magdeburg Germany;

Chemisches InstitutOtto‐von‐Guericke‐Universit?t MagdeburgUniversit?tsplatz 2 39106 Magdeburg Germany;

Chemisches InstitutOtto‐von‐Guericke‐Universit?t MagdeburgUniversit?tsplatz 2 39106 Magdeburg Germany;

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正文语种 eng
中图分类化学;
关键词
Triboluminescence; Lanthanides; Europium; β‐Diketonate; Crystal structure;

机译：焦虑;镧系;铕;铕;β-二氧酮;晶体结构;

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1. Two New Series of Potentially Triboluminescent Lanthanide(III) β‐Diketonate Complexes [J] . Margenfeld Leif‐Kenneth, Liebing Phil, Oehler Florian, Zeitschrift fur Anorganische und Allgemeine Chemie . 2018,第19期

机译：两种新的潜在累卷发镧系元素（III）β-二酮晶络合物
2. A series of dinuclear lanthanide(III) complexes constructed from Schiff base and beta-diketonate ligands: synthesis, structure, luminescence and SMM behavior [J] . Sun Ou, Chen Peng, Li Hong-Feng, CrystEngComm . 2016,第24期

机译：由席夫碱和β-二酮酸酯配体构建的一系列双核镧系元素（III）配合物：合成，结构，发光和SMM行为
3. A series of lanthanide(III) complexes constructed from Schiff base and beta-diketonate ligands [J] . Sun Ou, Gao Ting, Sun Jingwen, CrystEngComm . 2014,第45期

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4. Chapter 6 New Nanosized Systems Based Lanthanide Diketonate Complexes for OLEDs [C] . I. A. Savchenko, A. S. Berezhnytska, N. B. Ivakha, FP7 International Summer School "Nanotechnology: From Fundamental Research to Innovations" . 2015

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Two New Series of Potentially Triboluminescent Lanthanide(III) β‐Diketonate Complexes

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