首页> 外文期刊>Journal of chemical crystallography >Azinyl sulfides - Part 11 - 1-ethyl-3-methylthio-4-thioxo-1,4-dihydroquinoline or 1-ethyl-3-(methylthio)quinolinium-4-thiolate?
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Azinyl sulfides - Part 11 - 1-ethyl-3-methylthio-4-thioxo-1,4-dihydroquinoline or 1-ethyl-3-(methylthio)quinolinium-4-thiolate?

机译:硫酸硫化物 - 第11-1-乙基-3-甲基-4-硫代氧基-1,4-二氢喹啉或1-乙基-3-(甲硫基)喹啉-4-硫醇酸酯?

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摘要

The title compound 1 crystallizes in the monoclinic space group C2/c with a = 16.720(4), b = 8.577(1), c = 15.855(4) Angstrom, and beta = 98.37(1)degrees. The thiocarbonyl group C-S bond (1.697(4) Angstrom) is longer than those of typical carbon-sulfur double bonds in thiones. Bond lengths and bond angles in the pyridine ring of the title compound are close to the values found for pyridinium salts. [References: 24]
机译:标题化合物1在单斜晶间空间基团C 2 / C中结晶,其中A = 16.720(4),B = 8.577(1),C = 15.855(4)埃,β= 98.37(1)度。 硫代羰基C-S键(1.697(4)埃)比统一中的典型碳硫双键的键长。 标题化合物的吡啶环中的键长和键角接近吡啶盐的值。 [参考:24]

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