Synthesis and crystal structure of [~nBu_4N][Er(pic)_4]·5.5H_2O:a new infrared emitter

Paula C.R.Soares-Santos; Helena I.S.Nogueira; Vitor Felix; Tito Trindade; Rute A.Sa Ferreira; Luis D.Carlos; Michael G.B.Drew

首页> 外文期刊>Inorganic Chemistry Communications >Synthesis and crystal structure of [~nBu_4N][Er(pic)_4]·5.5H_2O:a new infrared emitter

【24h】

Synthesis and crystal structure of [~nBu_4N][Er(pic)_4]·5.5H_2O:a new infrared emitter

机译：[〜nBu_4N] [Er（pic）_4]·5.5H_2O的合成及晶体结构：新型红外发射器

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The new erbium (III) complex of picolinic acid (Hpic),[~nBu_4N][Er(pic)_4]·5.5H_2O,was synthesized and the crystal structure determined by single-crystal X-ray diffraction.The compound was further characterized using IR,Raman,~1H NMR and elemental analysis.The picolinate ligands (pic~-) are coordinated through N,O-chelation to the erbium cations,as shown by X-ray diffraction and spectroscopic results,leading to an eight coordiante complex.Photoluminescnece measurements were performed for this compound which exhibits infrared emission.

机译：合成了吡啶甲酸（Hpic）的新型（（III）络合物[〜nBu_4N] [Er（pic）_4]·5.5H_2O，并通过单晶X射线衍射确定了晶体结构。对该化合物进行了进一步表征X射线衍射和光谱分析结果表明，吡啶甲酸配体（pic〜-）通过N，O螯合与阳离子配位，通过X射线衍射和光谱分析表明，该配位体配位体（pic〜-）形成了8个co钴酸酯配合物对显示红外发射的该化合物进行光致荧光测量。

著录项

来源
《Inorganic Chemistry Communications》 |2003年第9期|共5页
作者
Paula C.R.Soares-Santos; Helena I.S.Nogueira; Vitor Felix; Tito Trindade; Rute A.Sa Ferreira; Luis D.Carlos; Michael G.B.Drew;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
erbium complexes; picolinic acid; crystal structure; photoluminescence;

机译：配合物;吡啶甲酸;晶体结构;光致发光;

相似文献

外文文献
中文文献
专利

1. Synthesis and crystal structure of [~nBu_4N][Er(pic)_4]·5.5H_2O:a new infrared emitter [J] . Paula C.R.Soares-Santos, Helena I.S.Nogueira, Vitor Felix, Inorganic Chemistry Communications . 2003,第9期

机译：[〜nBu_4N] [Er（pic）_4]·5.5H_2O的合成及晶体结构：新型红外发射器
2. X-ray crystal structure analysis of lanthanide trihydrogeno hydroxy-1-ethanebis(phosphonate)-1,1,dihydrogeno hydroxy-lethanebis(phosphonate)-1,1 hemiundecahydrate, Ln{[C(CH_3)(OH)(P_2O_6H_3)][C(CH_3)(OH)(P_2O_6H_2)]}·5.5H_2O with Ln = Y, Ho, Er; and [J] . L. Van Meervelt, P. Martello, J.-P. Silvestre, Zeitschrift fur Kristallographie: International Journal for Structural, Physical, and Chemical Aspects of Crystalline Materials . 2002,第1期

机译：镧系元素三氢羟基-1-乙烷双（膦酸酯）-1,1，二氢羟基乙烷双（膦酸酯）-1,1半不饱和水合物，Ln {[C（CH_3）（OH）（P_2O_6H_3）] [的X射线晶体结构分析C（CH_3）（OH）（P_2O_6H_2）]}·5.5H_2O，Ln = Y，Ho，Er;和
3. Lanthanide Complexes of 2,6-Dihydroxybenzoic Acid: Synthesis, Crystal Structures and Luminescent Properties of [nBu_4N]_2[Ln(2,6-dhb)_5(H_2O)_2] (Ln = Sm and Tb) [J] . Paula C. R. Soares-Santos, Helena I. S. Nogueira, Filipe A. Almeida Paz, European journal of inorganic chemistry . 2003,第19期

机译：2,6-二羟基苯甲酸镧系元素络合物：[nBu_4N] _2 [Ln（2,6-dhb）_5（H_2O）_2]（Ln = Sm和Tb）的合成，晶体结构和发光性能
4. Micro-machined infrared emitter with metallic photonic crystals structure [C] . Li Fangqiang, San Haisheng, Cheng Meiying, International symposium on advanced optical manufacturing and testing technologies;AOMATT08; 20081119-21;20081119-21; Chengdu(CN);Chengdu(CN) . 2008

机译：具有金属光子晶体结构的微加工红外发射器
5. Design, synthesis, and characterization of novel ligands containing seven -membered ring for the sensitization of near-infrared emitting lanthanide cations in complexes and nanocrystals [D] . Zhang, Jian 2008

机译：包含七元环的新型配体的设计，合成和表征，用于在配合物和纳米晶体中敏化近红外发射镧系元素阳离子
6. Controllable Synthesis of Monodisperse Er3+-Doped Lanthanide Oxyfluorides Nanocrystals with Intense Mid-Infrared Emission [O] . Huilin He, Qiang Liu, Dandan Yang, -1

机译：强烈的中红外发射可控制的单分散掺Er3 +掺杂的氟化镧氧化物纳米晶体的合成
7. Microwave assisted synthesis and characterizations of near infrared emitting Yb/Er doped fluorapatite nanoparticles [O] . S. Karthi, G. Suresh Kumar, G.A. Kumar, 2016

机译：微波辅助合成及近红外发射Yb / ER掺杂氟磷灰石纳米粒子的特征

Synthesis and crystal structure of [~nBu_4N][Er(pic)_4]·5.5H_2O:a new infrared emitter

摘要

著录项

相似文献

相关主题

期刊订阅