A lead(II)-orotate coordination polymer with a new coordination mode: Synthesis, structure and luminescent property

Hua Yin; Shi-Xiong Liu

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A lead(II)-orotate coordination polymer with a new coordination mode: Synthesis, structure and luminescent property

机译：具有新配位方式的乳清酸铅（II）配位聚合物：合成，结构和发光性能

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A lead(II) orotate complex [Pb(HOr)(H2O)]_n (1), (H3Or = orotic acid) was synthesized under hydrothermal condition and characterized by X-ray diffraction, IR, solid-state photoluminescence and thermogravimet-ric analysis. Lead atom in 1 is in a holodirected eight-coordinated polyhedron and the orotate ligand exhibits a new and unique hexametaltic coordination mode. The lead complex shows a 6,6-connected (4~8, 6~6, 8)(4~(13), 6~2) topology. The complex exhibits photoluminescence at 546 nm (λ_(ex) = 350 nm).

机译：在水热条件下合成乳清酸铅（II）配合物[Pb（HOr）（H2O）] _ n（1）（H3Or =乳清酸），并通过X射线衍射，IR，固态光致发光和热重分析表征分析。 1中的铅原子处于全取向八配位多面体中，乳清酸酯配体表现出新的独特六金属配位模式。铅络合物显示6,6-连接的（4〜8，6〜6，8）（4〜（13），6〜2）拓扑。该络合物在546nm（λ_（ex）＝ 350nm）处显示出光致发光。

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来源
《Inorganic Chemistry Communications》 |2009年第2期|共4页
作者
Hua Yin; Shi-Xiong Liu;
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原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
Lead(II); Complex; Crystal structure; Topology; Luminescent property;

机译：铅（II）;络合物;晶体结构;拓扑结构;发光性能;

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机译：具有新配位方式的乳清酸铅（II）配位聚合物：合成，结构和发光性能
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A lead(II)-orotate coordination polymer with a new coordination mode: Synthesis, structure and luminescent property

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