Crystal structure,magnetic and optical properties of(2-picoloylcarbonyl)thiosemicarbazonatocopper(II) ([Cu_3L_2(H_2O)_2] centre dot 2ClO_4 centre dot 3H_2O,and L = [C_7H_8N_4OS]~(2-))

Wen-Shi Wu; Wen-Dan Cheng; Dong-Sheng Wu; Hao Zhang; Ya-Jing Gong

首页> 外文期刊>Inorganic Chemistry Communications >Crystal structure,magnetic and optical properties of(2-picoloylcarbonyl)thiosemicarbazonatocopper(II) ([Cu_3L_2(H_2O)_2] centre dot 2ClO_4 centre dot 3H_2O,and L = [C_7H_8N_4OS]~(2-))

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Crystal structure,magnetic and optical properties of(2-picoloylcarbonyl)thiosemicarbazonatocopper(II) ([Cu_3L_2(H_2O)_2] centre dot 2ClO_4 centre dot 3H_2O,and L = [C_7H_8N_4OS]~(2-))

机译：（2-吡啶甲基羰基）硫代半碳氮杂铜（II）（[Cu_3L_2（H_2O）_2]中心点2ClO_4中心点3H_2O和L = [C_7H_8N_4OS]〜（2-）的晶体结构，磁性和光学性质

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摘要

Trinuclear copper(II)complex of [Cu_3L_2(H_2O)_2] centre dot 2ClO_4 centre dot 3H_2O was prepared by the reaction of(2-picoloylcarbonyl)thiosemicarba-zone(H_2L)and copper perchlorate hydrate,and the magnetic properties and absorption spectra were measured for the title compound,and the origin of third-order optical response was identified in terms of calculated results using density functional theory combined with sum-over-states methods.

机译：[Cu_3L_2（H_2O）_2]中心点2ClO_4中心点3H_2O的三核铜（II）配合物是由（2-吡啶甲酰基羰基）硫代半碳酸钠（H_2L）与水合高氯酸铜水合反应制得的通过使用密度泛函理论和求和状态法相结合的计算结果来确定标题化合物的三阶光学响应的起源。

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来源
《Inorganic Chemistry Communications》 |2006年第5期|共4页
作者
Wen-Shi Wu; Wen-Dan Cheng; Dong-Sheng Wu; Hao Zhang; Ya-Jing Gong;
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正文语种 eng
中图分类无机化学;
关键词
Trinuclear copper(II)complex; Thiosemicarbazone; Magnetic properties; Chromium; Third-order optical response; Crystal structure;

机译：三核铜（II）配合物;硫代氨基脲;磁性;铬;三级光学响应;晶体结构;

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1. Crystal structure,magnetic and optical properties of(2-picoloylcarbonyl)thiosemicarbazonatocopper(II) ([Cu_3L_2(H_2O)_2] centre dot 2ClO_4 centre dot 3H_2O,and L = [C_7H_8N_4OS]~(2-)) [J] . Wen-Shi Wu, Wen-Dan Cheng, Dong-Sheng Wu, Inorganic Chemistry Communications . 2006,第5期

机译：（2-吡啶甲基羰基）硫代半碳氮杂铜（II）（[Cu_3L_2（H_2O）_2]中心点2ClO_4中心点3H_2O和L = [C_7H_8N_4OS]〜（2-）的晶体结构，磁性和光学性质
2. The crystal structures of bis(oxalato)chromium(III) complexes with histamine and B_6 vitamin: Na[Cr(ox)_2(hm)] centre dot 3H_2O and Na[Cr(ox)_2(PM)] centre dot H_2O (hm, histamine; PM, pyridoxamine) [J] . Narumi Sakagami, Eva Kita, Przemyslaw Kita, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1999,第15期

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Crystal structure,magnetic and optical properties of(2-picoloylcarbonyl)thiosemicarbazonatocopper(II) ([Cu_3L_2(H_2O)_2] centre dot 2ClO_4 centre dot 3H_2O,and L = [C_7H_8N_4OS]~(2-))

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